FABRICATION OF PLASTIC SCINTILLATOR USING POLYSTYRENE MATRIX BASED

H. L. Nuri, M. Pancoko, Abdul Jami, H. Subhiyah, T. Ardiyati, Dian Maya Sari, A. T. Desviana
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Abstract

Experiments on making a plastic scintillator with polystyrene as a base material mixed with fluorescent compounds (primary and secondary dopants) have been performed. Primary dopants (PTP) used to produce emission at wavelengths of visible light and secondary dopants (POPOP) to shift the visible wavelengths to wavelengths that could be detected by Photomultiplier Tube (PMT) ) were carried out. Experiments were performed on the melting points condition of these materials, which had previously been subjected to a thermo-mechanical analysis using a Thermogravimetric Analysis-Differential Scanning Calorimetry (TGA-DSC) machine, where the melting point was in the range of 200-240°C. Furthermore, the fabrication was carried out using the extrusion technique, where polystyrene pellets mixed with PTP (1.5% by weight) and POPOP (0.05% by weight) were fed into an extrusion machine which has four hot areas to obtain a thin plate plastic scintillator. The plates were then analyzed with a UV-Vis Spectrophotometer to determine the absorption spectrum and Fluorescence Spectrophotometer to determine the emission spectrum. From the results of the analysis, it was found that the samples that went through scintillation pellets and without the addition of antioxidants had absorption spectrum data of 330 nm and emission spectrum of 421 nm. These values are in accordance with the characteristics of plastic scintillators on the market. 
聚苯乙烯基塑料闪烁体的制备
以聚苯乙烯为基材,与荧光化合物(一次和二次掺杂剂)混合,制备了塑料闪烁体。采用一次掺杂(PTP)产生可见光波长的发射,二次掺杂(POPOP)将可见光波长转移到光电倍增管(PMT)可探测的波长。在这些材料的熔点条件下进行实验,这些材料先前使用热重分析-差示扫描量热(TGA-DSC)机进行热力学分析,熔点在200-240°C范围内。在此基础上,采用挤压成形技术,将聚苯乙烯球团与PTP(重量比1.5%)和POPOP(重量比0.05%)混合,送入有四个热区的挤压机中,得到薄板塑料闪烁体。然后用紫外-可见分光光度计测定吸收光谱,荧光分光光度计测定发射光谱。从分析结果来看,未添加抗氧化剂的闪丸样品的吸收光谱数据为330 nm,发射光谱数据为421 nm。这些数值符合市场上塑料闪烁体的特点。
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