Investigation of the Composition and Mechanical Strength of Effective Thermoelectric Materials

M. Shtern, L. Matyna, M. Rogachev, Anton P. Merlyan
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Abstract

A review the synthesis of thermoelectric materials (TEM) and techniques of their subsequent processing in order to obtain an optimal structure was carried out. TEM on basis of BiTeSe and BiSbTe were obtained by zone melting and extrusion, and PbTe and GeTe were obtained by hot pressing. On basis of X-ray fluorescence analysis, a correlation was established between the concentration of elements in the initial composition and in the manufactured samples. The investigation of thermoelectric parameters of TEM was carried out. The thermoelectric figure of merit in the working temperature range varies from 1.05 to 1.20. Vickers microhardness was established that for BiTeSe and BiSbTe it is from 33.5 HV to 60.2 HV. The microhardness of PbTe and GeTe is 51.7 HV and 125.7 HV, respectively. The obtained results are necessary for the development of techniques for mechanical treatment of TEM and the design of thermoelectric devices.
有效热电材料的组成及机械强度研究
综述了热电材料(TEM)的合成及其后续加工技术,以获得最佳结构。在BiTeSe和BiSbTe的基础上,通过区熔和挤压得到TEM,通过热压得到PbTe和GeTe。在x射线荧光分析的基础上,建立了初始成分和制造样品中元素浓度之间的相关性。对TEM的热电参数进行了研究。工作温度范围内的热电优值从1.05到1.20不等。测定了BiTeSe和BiSbTe的维氏显微硬度在33.5 ~ 60.2 HV之间。PbTe和GeTe的显微硬度分别为51.7 HV和125.7 HV。所得结果对瞬变电磁学机械处理技术的发展和热电器件的设计是必要的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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