In-situ diagnostic of polypropylene degradation by electrical discharge induced luminescence at room temperature

M. Duran, G. Teyssèdre, F. Massines, C. Laurent
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Abstract

Cold electrical discharges or plasma are widely used to modify polymer properties whereas long interaction can lead to polymer degradation. Discharges are also commonly used to charge dielectric materials in order to study charge storage capabilities of the material and its evolution with time, using as example surface potential measurement. The interest of plasma-induced luminescence (PIL) technique would be to develop a new in-situ diagnostic of discharge-polymer interaction. The aim of the present work is to determine the way a plasma created by a cold electrical discharge can induce polymer luminescence at room temperature and how this PIL can be used for the diagnostic of polymer surface transformations and degradation.
室温下聚丙烯降解的放电致发光原位诊断
冷放电或等离子体被广泛用于修饰聚合物的性能,但长时间的相互作用会导致聚合物降解。为了研究材料的电荷存储能力及其随时间的演变,也常用放电对介电材料进行充电,以表面电位测量为例。等离子体诱导发光(PIL)技术的研究方向是开发一种新的放电-聚合物相互作用的原位诊断方法。本工作的目的是确定由冷放电产生的等离子体在室温下诱导聚合物发光的方式,以及如何将这种PIL用于聚合物表面转化和降解的诊断。
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