High-Pressure Processing: A Smart Way to Increase Energy Efficiency with Less Toxic Residues

G. Kravanja, M. K. Hrnčič, Darija Cör, Ž. Knez
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Abstract

High-pressure processes involving sub and supercritical fluids enable the design of products with special physical characteristics, less toxic residues, low energy consumption, and are eco-friendly and sustainable. Supercritical fluids show potential as solvents in boosting green chemistry by replacing environmentally harmful conventional organic solvents. Tunable physical properties of the supercritical fluids enable selective extraction, purification and fractionation of value-added products and by-products. Absorption of compressed gas in polymer matrices results in a wide spectrum of possible applications in the field of sustainable polymer processing, for example, production of fibers, microparticles and foams. As a heat transfer fluid, supercritical CO2 has been reintroduced as an environmentally friendly refrigerant in heat pumps working cycles. There is also great potential in the treatment of sewage wastes with supercritical fluids and production of value compounds from waste streams. Several supercritical fluid applications are presented from the perspective of their environmental and economic benefits.
高压处理:一种提高能源效率和减少有毒残留物的聪明方法
高压工艺涉及亚和超临界流体,使产品设计具有特殊的物理特性,毒性残留物少,能耗低,环保和可持续发展。超临界流体通过取代对环境有害的传统有机溶剂,在促进绿色化学方面显示出潜力。超临界流体具有可调的物理特性,可对增值产品和副产物进行选择性萃取、提纯和分馏。聚合物基质中压缩气体的吸收在可持续聚合物加工领域具有广泛的应用前景,例如,纤维、微粒和泡沫的生产。作为一种传热流体,超临界CO2作为一种环保制冷剂被重新引入热泵工作循环中。在用超临界流体处理污水废物和从废物流中生产有价值化合物方面也有很大的潜力。从环境效益和经济效益的角度介绍了几种超临界流体的应用。
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