An Innovative and Sustainable Portland Cement Alternative for Oil and Gas Wells

Andrey A. Yakovlev, V. Lafitte, S. Kapoor, M. Meade, W. Smith, Nathan Fischer, C. Parton, Veronica Richter McDonald, Yeukayi Nenjerama, Xia Wei, G. Landry
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Abstract

The manufacturing process of oilfield cement is one of the largest contributors to carbon emissions. Thus, finding sustainable alternative materials has become the main focus globally. Geopolymers are low carbon cement alternatives that have been used in the construction industry for many years, yet their applicability for oil and gas wells remains unproven. For geopolymers to be successfully implemented in the oilfield industry, a customization of the formulation is critical to eliminate logistical constraints and ensure compatibility with oilfield pumping equipment. Geopolymers are typically prepared with liquid alkaline activators, which render them impractical for onshore applications due to the complicated logistics of transporting liquids to a wellsite. Dry blending of the various components and handling constraints is an important condition for field use. A comprehensive lab study of geopolymer activator and functional additives was conducted. In the end, unique chemistries were identified that are compatible with dry blending and continuous live mixing for field application. A key focus was given to achieving parameters needed from operations, and compliance perceptive, and those which are comparable to the oilfield cements currently in use. Introducing an innovative geopolymer solid activator package enables mixing and pumping of geopolymer slurries without any modification of the current equipment or the job execution method and eliminate the need to handle corrosive liquids. After extensive lab studies, mixability, and pumpability of the newly designed geopolymer system was validated via yard trials. The current work has opened new avenues to make geopolymers adaptable to cementing land equipment while meeting the requirements needed to sustain performance under well conditions. This is a step change toward field deployment of a sustainable well integrity technology.
一种创新、可持续的油气井波特兰水泥替代品
油田水泥的制造过程是碳排放的最大贡献者之一。因此,寻找可持续的替代材料已成为全球关注的焦点。地聚合物是一种低碳水泥替代品,已在建筑行业使用多年,但其在油气井中的适用性尚未得到证实。为了在油田工业中成功应用地聚合物,定制配方对于消除物流限制并确保与油田泵送设备的兼容性至关重要。地聚合物通常是用液体碱性活化剂制备的,由于将液体运输到井场的物流复杂,因此不适合陆上应用。各种组分的干燥混合和处理约束是现场使用的重要条件。对地聚合物活化剂和功能助剂进行了综合实验室研究。最后,确定了适合干混和现场连续混炼的独特化学物质。重点是实现作业所需的参数、顺应性感知,以及与目前使用的油田水泥相媲美的参数。引入一种创新的地聚合物固体活化剂包,可以在不修改现有设备或工作执行方法的情况下混合和泵送地聚合物浆液,并且消除了处理腐蚀性液体的需要。经过大量的实验室研究,新设计的地聚合物体系的可混合性和可泵性通过现场试验得到了验证。目前的工作开辟了新的途径,使地聚合物适应于固井地面设备,同时满足在井况下保持性能所需的要求。这是向现场部署可持续井完整性技术迈出的一步。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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