Study of the Influence of the Additive "Polymateria" on the Ability to Biodegrade Polyethylene Films

I. Kirsh, I. Tveritnikova, O. Beznaeva, M. Gubanova, O. Bannikova, T. I. Chalykh
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Abstract

Introduction. The article is devoted to the study of the influence of the "Polymateria" additive on the properties of polyethylene films and their biodegradability. The additive "Polymateria" is presented by the manufacturer as an additive that accelerates the process of biodegradation of polyolefin films. However, studies published in the literature have not previously been presented.Purpose. Therefore, the purpose of the work is to study polymer films containing the Polymater additive for their performance characteristics and evaluate film samples for biodegradability. In the work, polymer films based on polyethylene and the additive "Polymateria" were obtained by extrusion.Materials and Methods. The following research methods were used in the work: a method for determining water absorption, a method for determining resistance to chemical media, a method for artificial aging of polymeric materials under the influence of ultraviolet radiation and temperature, a uniaxial tensile test method, comprehensive studies of films for biodegradation by composting, determination of the sanitary and hygienic properties of experimental samples during exposure in simulation environmentsResults. In the course of the study, it was found that the physical and mechanical properties under the influence of UV irradiation do not change as intensively as compared with the deformation-strength characteristics of samples that were subjected to artificial aging at temperature. It has been established that within 28 hours of exposure to thermal-oxidative aging, polyethylene films are destroyed and lose their integrity. It has been established that within 28 hours of exposure to thermal-oxidative aging, polyethylene films are destroyed and lose their integrity.In the process of composting, the relative elongation at break of samples treated with UV decreases by 1.5-2 times compared to the values ​​before composting. When composted for 7 months, the samples did not change their size, and their weight did not change either.Conclusion. Studies by the sanitary-chemical method made it possible to determine that in the environment of sodium chloride and distilled water after three weeks of exposure to polyethylene films containing the additive, a pungent odor is determined that exceeds the criterion of 2 points. Thus, such films cannot be used for food contact.
添加剂“Polymateria”对聚乙烯薄膜生物降解能力影响的研究
介绍。本文研究了“Polymateria”添加剂对聚乙烯薄膜性能及其生物降解性的影响。添加剂“Polymateria”是生产商介绍的一种加速聚烯烃薄膜生物降解过程的添加剂。然而,文献中发表的研究以前没有被提出过。因此,本工作的目的是研究含有Polymater添加剂的聚合物薄膜的性能特征,并评估膜样品的生物降解性。采用挤压法制备了以聚乙烯为基材,添加“Polymateria”的聚合物薄膜。材料与方法。工作中采用了以下研究方法:吸水率测定法、耐化学介质测定法、高分子材料在紫外线辐射和温度影响下的人工老化法、单轴拉伸试验法、堆肥生物降解膜的综合研究、实验样品在模拟环境中暴露时的卫生卫生性能测定。在研究过程中发现,与温度下人工老化的样品相比,紫外线辐照下的物理力学性能变化不大。已经确定,在28小时的热氧化老化中,聚乙烯薄膜被破坏并失去其完整性。已经确定,在28小时的热氧化老化中,聚乙烯薄膜被破坏并失去其完整性。在堆肥过程中,经过UV处理的样品的相对断裂伸长率比堆肥前降低了1.5-2倍。堆肥处理7个月后,样品的体积和重量均未发生变化。通过卫生化学方法的研究可以确定,在氯化钠和蒸馏水的环境中,暴露于含有添加剂的聚乙烯薄膜三周后,确定了超过2分标准的刺鼻气味。因此,这种薄膜不能用于食物接触。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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