Effects of ionic impurity on space charge distribution in solid dielectrics

M. Ezoe, K. Kuwada, T. Kawashima
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引用次数: 12

Abstract

We are interested in the interfacial phenomena concerning breakdown mechanism in solid dielectrics. We have been researching the effect of ionic impurity on space charge distribution and electric properties in filled epoxy resin and polyimide resin containing carbon. We have studied on the factors for hetero space charge accumulated near the electrodes by means of comparing the result of ionic analysis with the result of space charge behavior in high polymer this time. And we have guessed that hetero charge (positive charge) accumulated near the cathode are proton (H/sup +/) separated from organic acid, and negative charge accumulated near the anode are various -COO/sup -/ ions separated from organic acid.
离子杂质对固体介质中空间电荷分布的影响
我们对固体介质中与击穿机制有关的界面现象很感兴趣。研究了离子杂质对含碳填充环氧树脂和聚酰亚胺树脂空间电荷分布和电性能的影响。通过离子分析结果与高分子空间电荷行为结果的比较,研究了电极附近异位空间电荷积累的因素。我们猜测,在阴极附近积累的异电荷(正电荷)是从有机酸中分离出来的质子(H/sup +/),在阳极附近积累的负电荷是从有机酸中分离出来的各种- coo /sup -/离子。
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