Study of the dynamics of a four-module fuel cell stack to be integrated in a hybrid electric power plant of a utility vehicle

T. Romero, J. R. Flores, I. L. Albarrán, F. Loyola, Ulises Cano
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Abstract

A four-module PEM fuel cell stack was electrochemically characterized prior to its incorporation to a hybrid power plant of an electrical utility vehicle. The 3 kW fuel cell stack, comprised of 4 units of 100 membrane electrode assemblies (MEAs) in an open-cathode and air-cooled configuration, was characterized in order to identify its optimum operational parameters. The open cathode configuration is a common approach to reduce parasitic loads and increase energy efficiency in fuel cells; however, the forced convection derives frequently to internal dehydration. Voltage reversal caused by lack of reactants, many times due to dehydration at the reaction sites (membrane-electrode interface) is a common failure source for this kind of configuration especially at high current demands. Therefore, water management becomes crucial for preventing fuel cell's performance decrease and permanent failure. Subsequently, a smart water management strategy had to be established prior to the power plant integration into the vehicle for the fuel cell's performance to be guaranteed during the vehicle duty cycle. For this purpose, a testing protocol was established for testing each module based on linear voltammetries, electrochemical impedance spectroscopy and thermal images in order to observe cell's voltage and resistance as indicators of internal hydration, reactants concentration, and heat distribution during the stack operation. Polarization curves were obtained for each module and from them, the point (voltage, current, temperature and air vent) for steady operation was identified as the recommended condition for nominal performance during the fuel cell operation in the hybrid power plant of the electrical vehicle.
多功能车混合动力装置集成四模块燃料电池堆动力学研究
在将四模块PEM燃料电池堆集成到电动多功能车辆的混合动力装置之前,对其进行了电化学表征。为了确定最佳操作参数,研究人员对3kw燃料电池堆进行了表征,该燃料电池堆由4个单元的100个膜电极组件(MEAs)组成,采用开式阴极和气冷配置。在燃料电池中,开阴极结构是减少寄生负载和提高能源效率的常用方法;然而,强迫对流往往是由内部脱水引起的。由于反应部位(膜-电极界面)的脱水而导致的缺乏反应物引起的电压反转是这种配置的常见故障源,特别是在高电流需求时。因此,水的管理成为防止燃料电池性能下降和永久失效的关键。随后,必须在发电厂集成到车辆之前建立智能水管理策略,以保证燃料电池在车辆占空比期间的性能。为此,建立了基于线性伏安法、电化学阻抗谱法和热图像的测试方案,对各模块进行测试,以观察电池的电压和电阻作为堆叠过程中内部水化、反应物浓度和热量分布的指标。得到各模块的极化曲线,并据此确定燃料电池在电动汽车混合动力装置中运行时的稳定运行点(电压、电流、温度和通风量)为标称性能的推荐工况。
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