New route for sol-gel high-refractive-index ZrO2 coating

Yongxing Tang, Congshan Zhu, Weiqing Zhang, Zhong-hong Jiang
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Abstract

A new sol-gel route for zirconia coating is now reported. Zirconia coatings consisting of zirconia particles were prepared from inorganic precursor (ZrOCl28H2O) by a simple alcothermal process instead of the complicated hydrothermal method published by others. The coatings were applied by dip method. The zirconia coating structures and optical properties were investigated. The dependencies of coating thickness and refractive index on heat temperature were studied. It is noted that the abrasion resistance of coating is rapidly increased as cured temperature. The laser induced damage thresholds of zirconia coatings were range of 4 - 5 J/cm2, for 1 ns pulse width and 1064 nm wavelength. The relevant chemistry is discussed.
溶胶-凝胶高折射率ZrO2涂层新途径
报道了一种新的氧化锆溶胶-凝胶涂膜方法。以无机前驱体(ZrOCl28H2O)为原料,采用简单的醇热法制备了由氧化锆颗粒组成的氧化锆涂层。采用浸渍法涂覆涂层。研究了氧化锆涂层的结构和光学性能。研究了涂层厚度和折射率随热温度的变化规律。随着固化温度的升高,涂层的耐磨性迅速提高。激光损伤阈值范围为4 ~ 5 J/cm2,脉冲宽度为1ns,波长为1064nm。讨论了相关的化学问题。
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