Study on the Blending Characteristics of Ternary Cementless Materials

Yi-Hua Chang, L. Fiala, M. Záleská, D. Koňáková, W. Lin, A. Cheng
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Abstract

: In this study, three industrial by-products (ultrafine fly ash, ground granulated blast-furnace slag (ggbs) and circulating fluidized bed co-fired fly ash) were used to produce ternary cementless composites without using alkali activators. The finenesses of ultrafine fly ash, ggbs and co-fired fly ash were 33,800, 5830 and 5130 cm 2 /g, respectively. The composite material was developed by mixing supplementary cementing materials of different particle sizes and exploiting the high-alkaline properties of the co-fired fly ash to develop a substantial hardening property like cement. The test specimens were made in the form of pastes and the water-to-cementitious-material ratio for the test was fixed at 0.55. The test results show that the flowability of the six different mixtures could be up to 120% and the setting time could be controlled within 24 h. At 60% of the ggbs proportion, the setting time could be held for 8 h. The compressive strength of each proportion reached 7 MPa at 7 days and 14 MPa at 28 days. The water-cured specimens exhibited better strength behavior than the air-cured specimens. Scanning electron microscopy found the main components of strength growth of the specimens to be hydrated reactants of C-A-S-H or ettringite. The results of the XRF analysis show that the specimens responded to higher compressive strengths as the Ca/Si and Ca/Al ratios increased.
三元无水泥材料共混特性研究
本研究以三种工业副产品(超细粉煤灰、磨粒高炉渣和循环流化床共烧粉煤灰)为原料,在不使用碱活化剂的情况下制备三元无水泥复合材料。超细粉煤灰、矿渣和共烧粉煤灰的细度分别为33,800、5830和5130 cm 2 /g。该复合材料是通过混合不同粒径的补充胶凝材料,并利用共烧粉煤灰的高碱性来获得类似水泥的实质性硬化性能。试件以膏体形式制作,试验水胶料比固定为0.55。试验结果表明,6种混合料的流动性可达120%,凝结时间可控制在24 h以内,在ggbs比例为60%时,凝结时间可保持8 h, 7天抗压强度可达7 MPa, 28天抗压强度可达14 MPa。水固化试件的强度表现优于风干试件。扫描电镜发现试样强度增长的主要成分是C-A-S-H或钙矾石的水合反应物。XRF分析结果表明,随着Ca/Si和Ca/Al比的增大,试样的抗压强度增大。
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