Study on the transference of hydroplibocity for Kaolin and Kieselgur

Gongmao Peng, Z. Guan, Fuzeng Zhang, Liming Wang
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Abstract

As two of the inert materials which were widely used in the artificial pollution test and recommended by IEC standard, Kaolin and Kieselgur were studied in the paper. The DC flashover voltage of porcelain insulators which was contaminated by Kaolin was much closed to Kieselgur, and the same as glass insulators. But the conclusion was quiet different for composite insulator. The flashover voltage of polymeric insulator contaminated by Kieselgur was larger about 14.7% than Kaolin under the same condition because of their significant difference of transfer characteristics. The reason of hydrophobicity migration difference of the two is revealed by scanning electron microscope (SEM), ASAP 2020 specific surface area and porosity analyzer, thermogravimetric analysis (TG), and Fourier Transform Infrared Spectrum (FTIR), respectively. The result shows that the hydroxyl (-OH) within Kaolin molecular is an important reason that cause hydrophobicity migration difference of Kieselgur and Kaolin, other than microphysics structure, specific surface area, total pore volume, average pore diameter. The result can be adopted to give theoretical reference to lay down rule of DC artificial pollution test for composite insulator.
高岭土和基泽尔土的水亲和性迁移研究
作为国际电工委员会(IEC)标准推荐的两种广泛应用于人工污染试验的惰性材料,本文对高岭土和基泽尔土进行了研究。受高岭土污染的瓷绝缘子的直流闪络电压与基泽尔古非常接近,与玻璃绝缘子的直流闪络电压相当。但对于复合绝缘子,结论却截然不同。在相同条件下,基泽尔土污染的聚合物绝缘子的闪络电压比高岭土污染的聚合物绝缘子的闪络电压高14.7%,这是由于两者的传递特性存在显著差异。通过扫描电镜(SEM)、ASAP 2020比表面积和孔隙度分析仪、热重分析(TG)和傅里叶变换红外光谱(FTIR)分析了两者疏水迁移差异的原因。结果表明,除微物理结构、比表面积、总孔容、平均孔径外,高岭土分子内的羟基(-OH)是造成基色尔胶和高岭土疏水性迁移差异的重要原因。研究结果可为制定复合绝缘子直流人工污染试验规程提供理论参考。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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