Electron-Beam-Induced Deposition For Nanodevice Formation

M. Komuro
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Abstract

Electron-beam(EB) induced deposition will be very attractive method for producing nanometer-scale dots array to investigate single electron transport devices because of its simplicity without any successive processes such as etching and metal lift-off. In addition, there is the advantage of independent controllability of junction characteristics such as tunnel resistance and capacitance. In this work, hndamental properties of deposition process and deposits using m 6 gas are described. The EB system used here has been already reported, which can be evacuated down to Torr with the beam diameter of about 3nm with minimum increment of 2.5nm in deflection. The gas of w F 6 was introduced from the nozzle equipped in this system up to 1-2x Au electrodes with 0.8pm gap on SiOJSi substrate were used to measure the current-voltage(1-V) characteristics of wire, single tunnel junction and transistor At first, thickness profiles of deposited film is investigated, which is strongly dependent upon beam scanning method. It is revealed that secondary electrons generated by primary beam make a major role for chemical reaction from experiments and simulation Therefore the width of wire is about 13 nm in spite of the 3-nm incident beam. The resistivity of wires in the dose region more than 15pUshot is estimated to be less than 0.6mS1 cm and independent of the temperature between 230 and 300K. However at lower doses the resistance rapidly increases by 5 orders of magnitudes. In order to evaluate controllability of junction properties, tunnel barrier are produced. Most of I-V curves for them are fitted to Fowler-Nordheim plot a gradient of which changes systematically with the increase in designed space. This result indicates clearly the junction properties can be controlled at least with the accuracy of minimum deflection increment. From these results, the barrier height is estimated to be more than 0.2 eV. The reason for the lower barrier height is described. By using this technique, single electron transistors with in-plane gate are produced and electrical property shows Coulomb oscillation (drain current oscillation by gate modulation) at 230 K Torr following the EB exposure, where
电子束诱导沉积纳米器件的形成
电子束诱导沉积由于其简单,不需要蚀刻和金属剥离等连续过程,将成为研究纳米级单电子输运器件的极具吸引力的方法。此外,还具有隧道电阻和电容等结特性可独立控制的优点。本文介绍了m6气体沉积过程和沉积物的基本性质。本文所使用的EB系统已有报道,该系统的真空度可低至Torr,光束直径约为3nm,偏转最小增量为2.5nm。在SiOJSi衬底上,采用1-2x Au电极,以0.8pm的间隙测量导线、单隧道结和晶体管的电流-电压(1-V)特性。首先,研究了沉积膜的厚度分布,这在很大程度上取决于光束扫描法。实验和模拟结果表明,主光束产生的二次电子在化学反应中起主要作用,因此,尽管入射光束为3 nm,但线的宽度约为13 nm。在剂量大于15pUshot的区域,估计导线的电阻率小于0.6mS1 cm,与230 ~ 300K之间的温度无关。然而,在较低剂量下,耐药性迅速增加5个数量级。为了评价结性质的可控性,产生了隧道势垒。它们的大部分I-V曲线都拟合到Fowler-Nordheim图中,其梯度随设计空间的增加而系统变化。这一结果清楚地表明,至少可以用最小挠度增量的精度来控制结的性质。根据这些结果,势垒高度估计大于0.2 eV。描述了屏障高度较低的原因。通过使用该技术,可以生产出平面内栅极的单电子晶体管,其电学特性在230 K Torr下显示出库仑振荡(栅极调制的漏极电流振荡),其中
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