Contamination of the Dzheltulak-1 river basin under alluvial gold mining (the Amur region)

V. Radomskaya, S. Radomskiy, A. S. Segrenev, S. Kulik
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Abstract

The purpose of the introduced research is to study the environmental impact of placer gold mining. The object of the study is natural and natural-man-made geosystems of the Dzheltulak-1 river located in the Amur region. The content of the main cations and microelements in water samples was determined by atomic emission and mass spectral methods. The content of micro- and rock-forming elements in bottom sediments and soils was determined by X-ray fluorescence using XRF-1800 X-ray spectrometer (Shimadzu, Japan). The results of the conducted studies indicate that the contents of iron, manganese, copper, aluminum, vanadium, molybdenum, mercury and ammonium ions exceed commercial fishery standards in a significant part of the surface water samples. It is found out that settlement ponds negatively affect the water quality in the river Dzheltulak-1 downstream due to the dam drainage. The highest concentrations of dissolved forms of mercury were noted in the water of the settlement ponds. The gross content of arsenic in the samples of bottom sediments and soils exceeds sanitary and hygienic standards by 2.7–14.5 times. The distributions of mercury as the most dangerous pollutant among the biogenic components of geochemical landscape were worked out in detail. Mercury contamination of soils was classified according to the forms of mercury occurrence: free, physically sorbed, chemisorbed, sulfide and isomorphic. It has been shown that the free form is characteristic of fresh mercury contamination due to the use of prohibited technological schemes for gold-bearing sands separation by the amalgamation method.
冲积金矿开采对热尔图拉克1河流域的污染(阿穆尔河地区)
本研究的目的是研究砂金开采对环境的影响。研究的对象是位于阿穆尔河地区的Dzheltulak-1河的自然和自然-人造地质系统。采用原子发射法和质谱法测定了水样中主要阳离子和微量元素的含量。采用XRF-1800型x射线光谱仪(日本岛津),用x射线荧光法测定了海底沉积物和土壤中微量元素和成岩元素的含量。所进行的研究结果表明,在相当一部分地表水样品中,铁、锰、铜、铝、钒、钼、汞和铵离子的含量超过商业渔业标准。研究发现,由于大坝排水,沉降池对Dzheltulak-1河下游的水质产生了负面影响。在定居池塘的水中发现了最高浓度的溶解形式的汞。底泥和土壤样品中砷的总含量超过卫生卫生标准的2.7 ~ 14.5倍。详细计算了汞作为最危险污染物在地球化学景观生物成因组分中的分布。根据汞的赋存形式对土壤汞污染进行了分类:游离汞、物理吸附汞、化学吸附汞、硫化物汞和同构汞。由于采用了禁止的工艺方案,用汞合并法分离含金砂时,自由形态具有新鲜汞污染的特征。
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