{"title":"Initiation","authors":"","doi":"10.1163/9789004488380_004","DOIUrl":null,"url":null,"abstract":"1. explain why the radical halogenation of alkanes is not usually a particularly good method of preparing pure samples of alkyl halides. 2. use \\(\\ce{\\sf{C–H}}\\) bond energies to account for the fact that in radical chlorinations, the reactivity of hydrogen atoms decreases in the order \\[\\text{tertiary} > \\text{secondary} > \\text{primary}.\\] 3. predict the approximate ratio of the expected products from the monochlorination of a given alkane.","PeriodicalId":129263,"journal":{"name":"Out of the Cradle Endlessly Rocking","volume":"12 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2005-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Out of the Cradle Endlessly Rocking","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1163/9789004488380_004","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
1. explain why the radical halogenation of alkanes is not usually a particularly good method of preparing pure samples of alkyl halides. 2. use \(\ce{\sf{C–H}}\) bond energies to account for the fact that in radical chlorinations, the reactivity of hydrogen atoms decreases in the order \[\text{tertiary} > \text{secondary} > \text{primary}.\] 3. predict the approximate ratio of the expected products from the monochlorination of a given alkane.