Initiation

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Abstract

1. explain why the radical halogenation of alkanes is not usually a particularly good method of preparing pure samples of alkyl halides. 2. use \(\ce{\sf{C–H}}\) bond energies to account for the fact that in radical chlorinations, the reactivity of hydrogen atoms decreases in the order \[\text{tertiary} > \text{secondary} > \text{primary}.\] 3. predict the approximate ratio of the expected products from the monochlorination of a given alkane.
初始化
1. 解释为什么烷烃的自由基卤化通常不是制备纯烷基卤化物样品的特别好的方法。2. 用\(\ce{\sf{C–H}}\)键能来解释在自由基氯化反应中,氢原子的反应活性按\[\text{tertiary} > \text{secondary} > \text{primary}.\] 3的顺序递减的事实。预测给定烷烃单氯化反应中预期产物的大致比例。
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