Fabrication and Characterization of GO-Fe3O4/PSF Membrane with Phase Inversion Method

Vivia Maulida Alfianti, M. Munasir
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引用次数: 2

Abstract

Polysulfones are hydrophobic which can reduce membrane permeability. Permeability can be increased through the application of hydrophilic materials such as GO-Fe3O4 to the polysulfone membrane so that the membrane is hydrophilic. The riset purpose to determine the effect of the percentage weight of different material compositions on the hydrophilicity properties of the polysulfone membrane. Membrane fabrication is carried out using the phase inversion method where the polymer solution is molded in a place and immersed in a coagulation bath containing non-solvent. This solvent exchange causes the polymer to form a solid matrix and become a membrane. The results showed that GO particles were successfully doped with Fe3O4 material shown by XRD analysis at a peak of 35.61˚ with a magnetite phase, while FTIR analysis showed that there was an absorption band characteristic of Fe-O streching vibrations. The results of the contact angle test on the GO-Fe3O4/PSF membrane 0.75 wt per cent were around 73.17˚ which showed the smallest hydrophobic value and the membrane surface morphology had an average pore size of 333.61 nm so that the addition of GO-Fe3O4 composites could increase membrane hydrophilicity.
相转化法制备GO-Fe3O4/PSF膜及其表征
聚砜具有疏水性,可降低膜的通透性。通过在聚砜膜中加入GO-Fe3O4等亲水性材料,可以提高膜的渗透性,使膜具有亲水性。研究了不同材料组成的百分质量对聚砜膜亲水性的影响。膜的制造是使用相转化方法进行的,其中聚合物溶液在一个地方成型并浸入含有非溶剂的凝固浴中。这种溶剂交换使聚合物形成固体基质并成为膜。XRD分析结果表明,氧化石墨烯颗粒成功掺杂了Fe3O4材料,掺杂峰为35.61˚,具有磁铁矿相;FTIR分析结果表明,氧化石墨烯颗粒存在Fe-O拉伸振动的吸收带特征。结果表明,氧化石墨烯- fe3o4 /PSF膜的接触角在73.17˚左右,疏水性最小,膜表面平均孔径为333.61 nm,表明氧化石墨烯- fe3o4复合材料的加入可以提高膜的亲水性。
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