Towards High Performance CNT-Based Electrode Materials via Chemical Vapor Deposition Approach

A. M. Osman, R. Geioushy, O. Fouad
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Abstract

Recently, carbon nanotubes (CNTs) electrodes have increasingly attracted great attention in various applications such as energy storage, conductive adhesive; catalyst supports owing to their unique 1D tubular structure, high specific capacity, large surface area, and high electrical conductivity [1]. CNTs have high ability to mediate rapid electron transfer kinetics for a wide variety of electroactive species. Moreover, CNTs are easily modified and functionalized to suite different biological and environmental applications. However, the performance and the manufacture techniques of CNTs electrode have exposed to scientific researchers to be enhanced. CNTsbased electrodes could be fabricated via compressing and coating technologies. Unfortunately, these techniques have a negative impact on the adsorption performance of the electrode [2] as well as coating detachment after a short period [3]. At the present time, arc discharge, laser ablation, catalytic thermal decomposition and chemical vapor deposition (CVD) techniques have been used to synthesize CNTs [4,5]. Arc discharge and laser ablation are still not applicable in the industry due to the low mass production. Whereas, CVD performs a better production of large quantities of CNTs at a low cost, besides, the strong layer stuck over the substrate which in turn improves the performance of the electrode material and can be reused several times.
化学气相沉积法制备高性能碳纳米管基电极材料
近年来,碳纳米管(CNTs)电极在储能、导电粘接等领域的应用越来越受到人们的重视;催化剂载体具有独特的一维管状结构、高比容量、大表面积和高导电性[1]。碳纳米管具有很高的能力介导各种电活性物质的快速电子转移动力学。此外,碳纳米管易于修饰和功能化,以适应不同的生物和环境应用。然而,碳纳米管电极的性能和制造技术仍有待科学研究。基于碳纳米管的电极可以通过压缩和涂层技术制造。不幸的是,这些技术对电极的吸附性能有负面影响[2],并且在短时间内涂层脱落[3]。目前已采用电弧放电、激光烧蚀、催化热分解和化学气相沉积(CVD)等技术合成CNTs[4,5]。电弧放电和激光烧蚀由于批量生产规模小,在工业上还不适用。然而,CVD可以以较低的成本生产大量的碳纳米管,此外,牢固的碳纳米管层粘在衬底上,从而提高了电极材料的性能,并且可以多次重复使用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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