Heat Resistant Cu-Sn based Joint Paste for less than 30μm joint thickness

Hiroaki Ikeda, S. Sekine, Ryuji Kimura, Koichi Shimokawa, K. Okada, H. Shindo, T. Ooi, Rei Tamaki
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Abstract

We have developed a heat resistant joint paste by Cu-Sn IMCC (Intermetallic Compound Composite) for thin joint thickness. The developed IMCC paste contains only IMCC fine particles as a metal composite. Re-melting point of the paste can be above the sintering temperature. For example, 320C remelting point was observed by 280C sintering. The paste is adoptable for heat resistant joint. The paste also indicated there is no whisker in joint area after TCT 1,000cycles (-55~+175C). When the joint thickness to be thin, voids in the joint region becomes conspicuous. There are two root causes to form voids. The first is non-uniform interaction between joint material and objects (joint targets). The second is gas void. For the paste, we chose a simple composition using only IMC source (fine particles which already contains IMC micro-colonies in them) as a metal component to provide moderate and uniform interaction with joint targets. To eliminate gas voids, two-stage sintering process was adopted. The first sintering (pre-sintering) is to evaporate all volatiles from the paste and to make appropriate interconnection with the substrate keeping the paste shape convex and providing enough joint strength for subsequent cleaning treatments. The second sintering (main-sintering) is for the device joint to the paste without voids. For making thin joint thickness around 30μm, weak pressure onto the device (~0.7MPa) is effective. Test sample with Si die (700μm thick, 6mm width) with Ni/Au finished backside metal was mounted on to Cu substrate. The joint region is almost filled by grown IMC layers. The thickness of the joint region is 30μm for entire joint region without voids.
适用于接缝厚度小于30μm的耐热铜锡基接缝膏
研制了一种以铜锡金属间化合物复合材料(IMCC)为主要材料的耐高温接缝膏。所研制的IMCC膏体仅含有IMCC细颗粒作为金属复合材料。膏体的重熔点可高于烧结温度。以280℃烧结为例,重熔点为320℃。该膏体适用于耐热接缝。经TCT 1000次(-55~+175)后,关节部位无晶须。当节理厚度变薄时,节理区域的空洞变得明显。形成空洞有两个根本原因。首先是关节材料与物体(关节目标)之间的非均匀相互作用。第二种是气体空洞。对于膏体,我们选择了一种简单的组合物,仅使用IMC源(已经含有IMC微菌落的细颗粒)作为金属成分,以提供与联合目标适度均匀的相互作用。为消除气体空洞,采用两段烧结工艺。第一次烧结(预烧结)是蒸发膏体中的所有挥发物,并与基材进行适当的互连,保持膏体形状凸,并为后续的清洁处理提供足够的连接强度。第二次烧结(主烧结)是使装置与膏体无空隙接合。对于厚度在30μm左右的薄接头,对器件施加弱压力(~0.7MPa)是有效的。将背面金属为Ni/Au的Si模(700μm厚,6mm宽)的测试样品安装在Cu衬底上。节理区域几乎被生长的IMC层填充。整个节理区域厚度为30μm,无空洞。
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