Mercury Toxicity: Ecological Features of Organic Phase of Mercury in Biota- Part I

Loai Aljerf, Nuha AlMasri
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引用次数: 15

Abstract

Mercury is extensively used in industry with top usage in electrolytic chlorine. As a result of this elemental consumption in industry, different forms of inorganic and organic mercury get into the environment in great piles every day and many of these mercurial derivatives are converted to methylmercury by microorganisms. The study is assigned to inspect the ecological features of organic mercury species in biological and marine environments. In addition, the paper takes into account the uptake and the distribution of mercury in fish to investigate the conversion and mobilization of mercury from sediment deposits into the general environment. It has been confirmed that the biological half-life of methylmercury in human is about 70 days. In methodology, molecular identification of mercury has been defined. Monomethyl mercury in sediments was analyzed by gas chromatography (GC) hyphenated with electron capture detector (ECD) and the confirmation was measured by mass spectroscopy (MS). The conversion of mercury element to its organic species has been illustrated. In soil, it was found that lower pH favors monomethyl mercury and the higher pH, dimethylmercury formation, respectively. Dimethylmercury is the biological poisoning product and methylmercury is an artifact of isolation procedure. In next paper, we will turn to study the epidemiological features of organic phase of mercury and investigate in deep the distribution, metabolism, and toxicity of mercury and methylmercury in some essential raw food materials, domestic animal feedstock, and some other biological specimens using basically simple analytical methods of chromatography as paper (PC) and thin layer (TLC).
汞毒性:生物群中汞有机相的生态学特征-第一部分
汞广泛应用于工业,主要用于电解氯。由于工业中的这种元素消耗,每天都有大量不同形式的无机和有机汞进入环境,其中许多汞衍生物被微生物转化为甲基汞。该研究的目的是考察生物和海洋环境中有机汞物种的生态特征。此外,本文还考虑了汞在鱼类中的吸收和分布,以研究沉积物中汞的转化和动员到一般环境中的情况。经证实,甲基汞在人体内的生物半衰期约为70天。在方法学上,定义了汞的分子鉴定。采用气相色谱(GC)联用电子捕获检测器(ECD)对沉积物中的单甲基汞进行了分析,并采用质谱(MS)进行了确证。说明了汞元素向其有机形态的转化。在土壤中,较低的pH值有利于单甲基汞的形成,较高的pH值有利于二甲基汞的形成。二甲基汞是生物中毒产物,甲基汞是分离过程中的产物。在接下来的文章中,我们将转向研究汞的有机相的流行病学特征,并使用基本简单的色谱法如纸层(PC)和薄层(TLC)等分析方法,深入研究汞和甲基汞在一些重要的食品原料、家畜饲料和其他一些生物标本中的分布、代谢和毒性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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