Improved Dielectric Properties of Epoxy Nano Composites

Abstract

Epoxy-based nanodielectrics with 2, 5 and 7 wt.% of organically modified montmorillon - ite clay (oMMT) were prepared using high shear melt mixing technique. The interface of oMMT and epoxy of the nanodielectrics play a very important role in improving electri- cal, mechanical, thermal and wear properties. Therefore detailed study on the interfacial effects of filler-matrix has been investigated for understanding the chemical bonding using Fourier transform infrared spectroscopy (FTIR) and the cross linking between polymer and filler was studied using glass transition temperature (T g ) through differ - ential scanning calorimetry (DSC). Further, positron annihilation lifetime spectroscopy (PALS) was used to determine precise and accurate value of free volume of the nanodi- electrics. The interaction between the nanoparticles and polymer chains has a direct bear-ing on dielectric strength characteristics of the epoxy-oMMT nanocomposite system and accordingly, the ac dielectric strength of the nanodielectrics increases with the addition of oMMT into epoxy up to 5 wt.% and further increase in filler loading (7 wt.%) causes decrease in ac dielectric strength.