Fluorescent carbon quantum dots formed from glucose solution by microplasma treatment

A. Tyutrin, R. Wang, E. F. Martynovich
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引用次数: 1

Abstract

Carbon quantum dots (CQDs) were synthesized of glucose solution by microplasma treatment at atmospheric pressure and room temperature. The spectral-kinetic properties of the synthesized CQDs were studied use of MicroTime 200 confocal scanning luminescence microscope. СQDs have a wide emission spectrum in 400–750 nm area when excited by light with wavelength in the 375–530 nm range. CQD exhibit a bright radiation in the blue range. The concentration of quantum dots was controlled by varying the time of microplasma treatment of glucose solution. The time-resolved fluorescence decay curve was measured by the time-correlated single photon counting (TCSPC) method. Studies of luminescence kinetics revealed three exponential components with decay time constants equal to 0.65, 2.2, and 6.2 ns. The formation of these components is presumably associated with the quantum confinement effect and with presence of different functional groups between which quantum transitions take place.
用微等离子体处理葡萄糖溶液形成荧光碳量子点
采用微等离子体法制备葡萄糖溶液,在常压和室温下制备了碳量子点(CQDs)。利用MicroTime 200共聚焦扫描发光显微镜研究了合成的CQDs的光谱动力学性质。СQDs在被波长为375-530 nm的光激发时,在400-750 nm区域有较宽的发射光谱。CQD在蓝色范围内显示出明亮的辐射。通过改变微等离子体处理葡萄糖溶液的时间来控制量子点的浓度。用时间相关单光子计数(TCSPC)法测定了时间分辨荧光衰减曲线。发光动力学研究表明,其衰变时间常数分别为0.65、2.2和6.2 ns。这些成分的形成可能与量子约束效应和发生量子跃迁的不同官能团的存在有关。
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