Graphite/UPE Nanocomposite: Transport, Thermal, Mechanical and Viscoelastic Properties

Shivkumari Panda, D. Behera, T. Bastia
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Abstract

This chapter presents the preparation and characterization of some unique properties of nanocomposites by dispersing graphite flakes in commercial unsaturated polyester (UPE) matrix. The composite was prepared by a novel method with the use of solvent swelling technique. Three different specimens of UPE/graphite nanocomposites were fabricated with addition of 1, 2 and 3 wt% of graphite flakes. Except mechanical, viscoelastic and thermo gravimetric properties, transport properties like electrical conductivity, thermal conductivity and water transport properties were studied for the first time. Graphite flakes propose enhanced properties to the composites suggesting homogeneous distribution of the nanofiller in the matrix and strong interaction with the matrix. 2wt% nanofiller loading showed superior essential characteristics and after that the properties reduced may be due to the nucleating tendency of the nanofiller particles. The XRD pattern showed the compatibility of the graphite flakes by introducing a peak around 26.550 in the nanocomposites. SEM Properties are also in agreement with the compatibility. Nanocomposite with 2wt% graphite also showed remarkable enhancement in transport, mechanical, viscoelastic and thermo gravimetric properties. So by introduction of a small quantity of graphite endow the new class of multiphase nanocomposites with inimitable structure and tremendous application.
石墨/聚乙烯纳米复合材料:传输、热、机械和粘弹性性能
本章介绍了将石墨片分散在工业不饱和聚酯(UPE)基体上的纳米复合材料的制备和一些独特性能的表征。采用溶剂溶胀法制备了该复合材料。分别添加1、2、3 wt%的石墨薄片制备了3种不同的UPE/石墨纳米复合材料试样。除力学、粘弹性和热重性能外,还首次研究了导电率、导热率和水输运性能。石墨薄片增强了复合材料的性能,表明纳米填料在基体中的均匀分布以及与基体的强相互作用。纳米填料填充量为2wt%时表现出较好的本质特性,超过2wt%后性能下降可能是由于纳米填料颗粒的成核倾向所致。XRD谱图表明,复合材料在26.550附近有一个峰,表明了石墨片的相容性。SEM性质也与相容性一致。石墨含量为2wt%的纳米复合材料在输运、力学、粘弹性和热重性能方面也有显著提高。因此,少量石墨的引入赋予了多相纳米复合材料以独特的结构和巨大的应用前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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