Study of BOF slags properties with the purpose of their utilization technology perfection

Abstract

Actuality of steel-making slags utilization is stipulated not only by the necessity to improve ecology situation at the sites of slag piles, but also by a possibility to obtain additional raw materials for metallurgical production. Increase of the domestic iron-containing raw materials at Magnitogorsky steel-works can be done by more effective processing of steel-making slags. To improve the technology of BOF slags processing, a work done to study their chemical and mineral composition. It was established, that primary and secondary BOF slags are attributed to basic and ultra-basic, since the SiO2 mass share is less than 25–40%. Petrographic study results and data of IR-spectroscopy showed, that larnite, alite, monticellite and oxide RO-phase (Fe2+, Mn2+, Mg2+)O are main mineral components of the BOF slags. In many cases, the structure of the secondary BOF slags has middle-size grains, and the structure of primary slags is fine-grained. The texture of the secondary and primary slag is more often massive. The BOF slags have globules of iron, the size of which varies from sub-millimeters up to 5 mm. Study of influence of various methods of BOF slag particles destruction on the degree of globules disclosure showed, that application of centrifugal-striking crushing facilities provides more selective globules disclosure comparing with other methods. It was proved, that dry magnetic separation in suspended state, due to its peculiarities, provides higher technological indices comparing with drum separator when separating fine slags even at increase material moisture up to 5%.