Adsorption of Pb2+ Ions Aqueous Environment Using the Novel CaoCdo/Zsm-5 Zeolite Nanocomposite Adsorbent

M. Sadeghi, Pourya Zarshenas
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Abstract

ZSM-5 is a porous zeolite material that reveals good activity for the adsorption of heavy metals and other contaminants for effluent purification. In this scientific research, we synthesized the novel CaO-CdO/ZSM-5 zeolite nanocomposite adsorbent and studied the effects of different parameters on the adsorption of Pb2+ ions from water media for the first time. About 99.2% adsorption removal efficiency was obtained after contact time of 60 min and adsorbent amount of 0.1 g/L for initial Pb2+ concentration of 200 mg/L at pH8 and temperature of 60o C. The adsorption kinetic fit well via the pseudo-second order model. Furthermore, the adsorption results were reproduced using the Langmuir isotherm with a maximum adsorption capacity of mg/g. The thermodynamic data displayed that the adsorption of Pb2+ ions over the CaO-CdO/ZSM-5 nanocomposite were endothermic and spontaneous.
新型CaoCdo/Zsm-5沸石纳米复合吸附剂对水中环境中Pb2+离子的吸附
ZSM-5是一种多孔沸石材料,具有良好的吸附重金属和其他污染物的活性,用于污水净化。本文首次合成了新型的CaO-CdO/ZSM-5分子筛纳米复合吸附剂,并研究了不同参数对吸附水中Pb2+离子的影响。当ph为8,温度为60℃,初始Pb2+浓度为200 mg/L,吸附时间为60 min,吸附剂用量为0.1 g/L时,吸附去除率为99.2%,吸附动力学符合准二级模型。在最大吸附量为mg/g的条件下,用Langmuir等温线重现了吸附结果。热力学数据表明,Pb2+离子在CaO-CdO/ZSM-5纳米复合材料上的吸附是吸热自发的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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