Electrical and Thermal Properties of C60‐filled Single Wall Carbon Nanotubes

J. Vavro, M. Llaguno, B. Satishkumar, R. Haggenmueller, K. Winey, D. Luzzi, J. Fischer, G. Sumanasekera, P. Eklund
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引用次数: 3

Abstract

We measured temperature‐dependent resistivity ρ, thermal conductivity κ and thermopower S of C60@SWNT (“peapods”). C60 filling reduces ρ much less than alkali metal doping at all T, indicating weak charge transfer. κ is enhanced by filling, the enhancement showing interesting structure vs. T for which we give a tentative explanation. S is reduced at all T by C60 filling, which we explain by a) C60@SWNT blocking some of the oxygen doping sites, and b) weak disorder on the 1‐D chain which reduces the mean free path of tube phonons and thus the phonon drag contribution.
C60填充单壁碳纳米管的电学和热学性能
我们测量了C60@SWNT(“豆荚”)的温度相关电阻率ρ、导热系数κ和热功率S。C60填充对ρ的降低远远小于碱金属掺杂,表明弱电荷转移。κ通过填充得到增强,与T相比,这种增强显示出有趣的结构,对此我们给出了初步的解释。S在所有T处都被C60填充减少了,这可以解释为a) C60@SWNT阻塞了一些氧掺杂位点,b) 1 - D链上的弱无序减少了管声子的平均自由程,从而减少了声子阻力的贡献。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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