Electric Resistance of Photosensitive Bichromate Polymers

Shin Suzuki, K. Aisaka
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Abstract

Photosensitive polymers which are known as non-silver photosensitive substance became insoluble to the original solvent through the progress of hardening process by exposing to ultra violet ray. The electric resistance of bichromate sensitive polymers were measured under the exposure of light. Potassium bichromate which was irradiated by gamma-ray was also employed for the specimen of this study. It was supposed that hardening reaction of water soluble polymers coexisted with bichromate salt was initiated by photoreduction of Cr6+ to Cr3+, and then the hardening rea ction of water soluble polymers by Cr3+ was Proceeded1) 2) . In order to ascertain the hypothesis, the authors also measured the dark electric resistance of potassium bichromate gelatin to which Cr3+ was added.
感光重铬酸盐聚合物的电阻
光敏聚合物被称为非银光敏物质,它在紫外线照射下经过硬化过程而不溶于原始溶剂。测定了重铬酸盐敏感聚合物在光照下的电阻。本研究的样品也采用了伽玛射线辐照的重铬酸钾。我们认为,与重铬酸盐共存的水溶性聚合物的硬化反应是由Cr6+光还原成Cr3+引发的,然后再进行Cr3+对水溶性聚合物的硬化反应1)2)。为了证实这一假设,作者还测量了加入Cr3+的重铬酸钾明胶的暗电阻。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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