Enhance of Sensitivity of Corrole Functionalized Polymeric Microspheres Coated Quartz Microbalances

Andrea Savoldelli, G. Magna, S. Nardis, F. Fronczek, Kevin M Smith, C. Natale, R. Paolesse
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Abstract

An innovative and efficient β-functionalization of [5,10,15-tris-(4-methylphenyl)corrolato]Cobalt derivatives introduced an acrolein substituent, which allowed the copolymerization with pure acrolein. The obtained hybrid microparticles have been used as sensing materials of quart microbalance gas sensors. The sensing properties have been tested by exposure to different volatile organic compounds chosen as model analytes. Results show an improved sensitivity of the hybrid microparticles respect to the individual constituents.
改性高分子微球包覆石英微天平灵敏度的提高
[5,10,15-三-(4-甲基苯基)腐蚀]钴衍生物的创新和高效β功能化引入了丙烯醛取代基,使其能够与纯丙烯醛共聚。所获得的杂化微粒已被用作夸脱微天平气体传感器的传感材料。通过暴露于选择作为模型分析物的不同挥发性有机化合物,测试了传感性能。结果表明,杂交微粒对单个成分的敏感性有所提高。
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