Development of Optimized Welding Consumable for Joining Type 410 Martensitic Stainless Steel

B. J. Lawson, B. Alexandrov, J. Bundy, D. Benson, J. Penso
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Abstract

Type 410 martensitic stainless steel is used in some downstream hydro-processing installations, due to its good resistance to sulfide corrosion and chloride stress corrosion cracking. Industry experience with Type 410 steel welds, using generic welding consumables, has shown difficulties in meeting the weld metal and HAZ hardness and toughness requirements. Recent research has pointed out the wide composition specifications of Type 410 base metal and welding consumables as the leading cause for significant hardness and toughness variations, related to exceeding the A1 temperature during PWHT and formation of fresh martensite, and to retention of significant amounts of delta ferrite. Predictive equations for the A1 temperature and the content of retained delta ferrite were used to identify optimal composition for Type 410 welding consumables with delta ferrite content below 20% and A1 temperature close to the upper end of the ASME specified PWHT range. Experimental metal core filler wire was manufactured and tested to validate the A1 temperature and delta ferrite content. A test weld in Type 410 steel was produced with the new filler wire and subjected to PWHT, metallurgical characterization, and mechanical testing. The weld metal and HAZ properties met the corresponding NACE and ASME hardness and toughness requirements.
410型马氏体不锈钢焊接优化耗材的研制
410型马氏体不锈钢由于具有良好的抗硫化物腐蚀和氯化物应力腐蚀开裂的性能,在一些下游加氢装置中使用。使用通用焊材的410型钢焊缝的工业经验表明,在满足焊缝金属和HAZ硬度和韧性要求方面存在困难。最近的研究指出,410型母材和焊材的广泛成分规格是造成硬度和韧性显著变化的主要原因,这与PWHT过程中超过A1温度和形成新的马氏体以及保留大量的δ铁素体有关。利用A1温度和残留δ铁素体含量的预测方程,确定了δ铁素体含量低于20%、A1温度接近ASME规定PWHT范围上限的410型焊材的最佳成分。制作了实验金属芯填充丝,并对其A1温度和δ铁氧体含量进行了验证。用新型焊丝制作了410型钢的试验焊缝,并进行了PWHT、冶金性能和力学性能测试。焊缝金属和HAZ性能均满足相应的NACE和ASME硬度和韧性要求。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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