Physicochemical, Fatty Acid and Sensory Profile of Cocoa Butter Produced from Fermented and Non-Fermented Cocoa Butter

Novia Andriani, R. Yenrina, N. Nazir
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Abstract

The study aimed to explore the influence of fermentation and non-fermentation on cocoa processing (Theobroma cacao L.) on physical properties, chemical properties, fatty acid profiles and sensory properties of cococa butter. The study was conducted using an experimental method with two treatments and three replications. Analysis of cocoa butter consisted of yield, color, moisture content, free fatty acids,  iod numbers, peroxide numbers, determination of fatty acid profile using GC-MS, and analysis of sensory properties. The results showed that the yield was between 20.82-21.00%. The color of fermented cocoa butter has a value of L* 17.88, a*8.70, and b*7.99 while for nonfermented cocoa butter has a value of L* 14.88, a* 8.96, and b* 6.78, water content between 0.10-0.12%, free fatty acids 0.51-0.56%, iod numbers 26.40-26.50 g I2/100g, peroxide numbers between 0.40-0.70 meq peroxide/kg fat, 190.23-191.40 mg KOH/g fat. The fatty acid profile using GC-MS showed that the dominant fatty acid constituents contained in fermented and nonfermented cocoa fats are oleic acid (29.39-29.57%), heptadecanoic acid (25.85-26.77%), and palmitic acid (21.49-21.83%).  Based on sensory analysis of cocoa butter with fermented treatment is preferred because it has a more attractive color, taste, and aroma compared to nonfermented cocoa butter.
发酵和非发酵可可脂的理化、脂肪酸和感官特征
本研究旨在探讨可可加工过程中发酵和非发酵对可可脂物理性质、化学性质、脂肪酸谱和感官性质的影响。本研究采用两处理三重复的实验方法进行。可可脂的分析包括产量、颜色、水分、游离脂肪酸、碘含量、过氧化物含量、气相色谱-质谱法测定脂肪酸谱和感官特性分析。结果表明,产率在20.82 ~ 21.00%之间。发酵后的可可脂颜色为L* 17.88、a*8.70、b*7.99,未发酵的可可脂颜色为L* 14.88、a* 8.96、b* 6.78,含水量为0.10 ~ 0.12%,游离脂肪酸为0.51 ~ 0.56%,碘含量为26.40 ~ 26.50 g /100g,过氧化物含量为0.40 ~ 0.70 meq /kg脂肪,过氧化物含量为190.23 ~ 191.40 mg KOH/g脂肪。通过气相色谱-质谱分析可知,发酵和非发酵可可脂肪的主要脂肪酸成分为油酸(29.39 ~ 29.57%)、十六烷酸(25.85 ~ 26.77%)和棕榈酸(21.49 ~ 21.83%)。根据感官分析,经过发酵处理的可可脂是首选,因为与未发酵的可可脂相比,它具有更吸引人的颜色,味道和香气。
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