Comparative Study of High Temperature Oxidation of Mild Steel in Hydrogen, Sulphur, and Carbon dioxide Atmospheres

O. W. Obot, Chinda Believe Chibuike
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Abstract

Fabricated materials made from mild steel tend to corrode when exposed to the atmosphere overtime, and often result mostly in the complete failure of materials while in service. This research aimed at establishing the relationship between oxidation of mild steel and temperature; the comparison of oxidation of mild steel at high temperature in different atmospheres, and the calculation of the rate of oxidation of mild steel at elevated temperatures. Mild steel finds application in weldable boiler tubes and in weldable turbines requiring very high temperature for its operation, hence this research was carried out at a maximum temperature of 1000 OC and samples were pre-treated in the different atmospheres for 96 hours intervals for 480 hours. The mild steel samples used in this research were labelled samples 1 and 2 and composed 0.19875 %C and 0.19220 %C, respectively. The atmospheres in which the experiment was carried out included hydrogen, sulphur and carbon dioxide.  The result of the experiment showed that the rate of oxidation of mild steel followed parabolic relationship, also the rates were different in the different atmospheres and the highest rate occurred in carbon dioxide.
低碳钢在氢、硫和二氧化碳环境中高温氧化的比较研究
由低碳钢制成的制造材料在长时间暴露于大气中时容易腐蚀,并且常常导致材料在使用期间完全失效。本研究旨在建立低碳钢氧化与温度的关系;比较了不同气氛下低碳钢在高温下的氧化情况,计算了低碳钢在高温下的氧化速率。低碳钢适用于可焊接的锅炉管和可焊接的涡轮机,其操作需要非常高的温度,因此本研究在1000℃的最高温度下进行,样品在不同的气氛中预处理96小时,间隔480小时。本研究中使用的低碳钢样品标记为样品1和样品2,分别由0.19875% C和0.19220% C组成。进行实验的环境包括氢、硫和二氧化碳。实验结果表明,低碳钢的氧化速率呈抛物线关系,且在不同的气氛中氧化速率不同,在二氧化碳中氧化速率最高。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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