Effect of metal-dielectric environments on spontaneous emission and concentration quenching of HITC laser dye

Abstract

We have studied the effects of planar, lamellar, and random nanostructured metal-dielectric environments on spontaneous emission and energy transfer concentration quenching of HITC laser dye. We found an inhibition of the concentration quenching in vicinity of metal, which was stronger in nanostructured substrates than in plain geometries. It was shown that the same substrates, which boosted spontaneous emission, also inhibited the concentration quenching. The effect is discussed in terms of the Forster radius affected by losses. Work at LLNL was performed under the auspices of the U.S. Department of Energy by LLNL under Contract DE-AC52-07NA27344