Restoration Technology of Contaminated Sediments in Coastal Environments using Steel-making Slag in Korea

Kwang-Seok Park, Hyung-Suek Kim, Ki-Young Park
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Abstract

This research was conducted to investigate the possibility of applying steel-making slag as a capping (or covering) material for the remediation of polluted sea sediments and to restore the productivity in polluted marine culturing grounds and seawater quality ultimately. Steel-making slag obtained from the Kwangyang Works of POSCO were scattered in the area of 100 M x 200 M, which is located in Go-sung Bay of southern part of Korean Peninsula. The diameter of slag less than 5~8 mm was scattered using a spreading machine until the slag layer on sea sediments reached thickness between 0.5 and 1.0 cm. From these large-scale experiments for more than 12 months, PO4-P and H2S liberations from the polluted sediment resulted to be suppressed to the extent of above 95% and 97%, respectively. Applying steel-making slag on the seawater quality was determined to be not harmful in the view of pH and leached trace metal concentrations. Furthermore, applying steel-making slag resulted in much higher survival rate of phytoplankton than that from the original area. The beneficial effects of steel-making slag were evident in the sense of elevated population of phytoplankton in middle and lower water layer on the slag covered area. The growth indexes of oyster such as shell length, height, width, and wet weight in steel slag scattering area were also higher than those from the original area. In addition, higher contents of protein and fatty acid including EPA and DHA were found in the body of oyster cultured in slag-covered area. No evidence of secondary contamination from steel-making slag was found in the body of oyster.
利用韩国炼钢渣修复沿海环境污染沉积物的技术
本研究旨在探讨利用炼钢渣作为封盖(或覆盖)材料修复受污染海洋沉积物的可能性,最终恢复受污染海洋养殖场的生产力和海水质量。从浦项制铁光阳工厂回收的炼钢渣散落在位于韩半岛南部高成湾的100米× 200米的区域内。对直径小于5~ 8mm的矿渣采用铺渣机进行撒渣,使其在海沉积物上的矿渣层厚度达到0.5 ~ 1.0 cm。在12个月以上的大规模试验中,污染沉积物的PO4-P和H2S释放分别被抑制了95%和97%以上。从pH值和浸出的微量金属浓度等方面确定炼钢渣对海水水质无害。施用炼钢渣后,浮游植物的成活率明显高于原生区。炼钢渣的有利作用表现在提高了中下层水层浮游植物种群对炼钢渣覆盖面积的影响。钢渣散射区牡蛎的壳长、高、宽、湿重等生长指标均高于原生区。此外,在覆渣区养殖的牡蛎体内含有较高的蛋白质和脂肪酸,包括EPA和DHA。牡蛎体内未发现炼钢渣二次污染的证据。
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