Exploring Opportunities for Capacity Enhancement in Sour Gas Treatment Unit

S. Deshpande, J. Sukanandan
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Abstract

Methyl Di-ethanol Amine (MDEA) based Gas Sweetening Process is an established process for treatment of sour gases to meet pipeline specifications with regards to H2S contents. One of the Gas Sweeting Unit (GSU) has been designed with generic MDEA solvent to selectively remove H2S along with 32% Co-absorption of CO2. It was observed that because of higher receipt of sour gas, all GSU trains were operating with higher feed gas throughput resulting in higher H2S content in sweet gas & higher quantity of acid gas generation. A detailed study was carried out to explore the possibilities for maintaining sweet gas quality with increased sour gas throughput. Detailed simulation studies on "HYSYS" process simulator revealed, that using generic MDEA it was difficult to increase the operating capacity of the GSU while maintaining H2S content in sweet gas & acid gas quantity generation within acceptable limits. Hence opportunities for speciality amines were explored. Case studies revealed successful use of specialty amines for capacity enhancement and improved performance in the existing system. With the targeted sweet gas quality, the capacity can be enhanced up to 30% with minor modifications in the existing set up. This also resulted in significant reduction in consumption of utilities like steam, power and cooling water.
探索提高酸性气体处理装置产能的机会
基于甲基二乙醇胺(MDEA)的气体脱硫工艺是一种成熟的工艺,用于处理含硫气体,以满足管道对H2S含量的要求。采用通用MDEA溶剂设计了一套气体脱硫装置(GSU),可选择性脱除H2S, CO2共吸收率为32%。研究发现,由于酸性气体的接收量增加,所有GSU列车都以更高的原料气吞吐量运行,从而导致甜气中H2S含量增加和酸性气体产生量增加。详细研究了在提高含酸气产量的情况下保持含硫气质量的可能性。在“HYSYS”过程模拟器上进行的详细仿真研究表明,使用通用MDEA很难在提高GSU运行能力的同时,将甜气中H2S含量和酸气量保持在可接受的范围内。因此,探索了特种胺的机会。案例研究表明,在现有系统中成功地使用了特种胺来增强能力和改善性能。有了目标的含硫气体质量,只要对现有装置进行微小的修改,产能就可以提高30%。这也大大减少了蒸汽、电力和冷却水等公用事业的消耗。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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