The Measurement and Prediction of Flash Point for Binary Mixtures {C1 ~ C3 Alcohols + p-Xylene} at 101.3 kPa

Abstract

The flash point of flammable liquid mixture is very important parameter to characterize the ignition and explosion hazards. Flash points at 101.3 kPa were measured for several binary systems containing p-xylene, including {methanol + p-xylene}, {ethanol + p-xylene}, and {2-propanol and p-xylene}. Experimental measurements were performed using a SETA closed cup flash point tester. The measured flash points were compared with the predicted values calculated using the following activity coefficient models: Wilson, Non-Random Two Liquid (NRTL), and UNIversal QUAsi-Chemical (UNIQUAC). The results from the NRTL model provided the best comparison to the experimentally determined values.