New Perspectives of the Silicates Based Materials: From Classical To Emerging Applications of Glasses

C. Ilie, Ludmila Motelica, D. Ficai, R. Trusca, O. Oprea, A. Ficai
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Abstract

Silicon and oxygen are some of the most abundant elements of the earth being mainly found in the nature as silicates. Among many applications, large amounts of glasses are produced for many specific applications. However, there are some emerging applications which are increasingly gaining attention. The classical applications of the glass involve windows (automotive, house, etc.), glass fibers and fabrics (resin based composites with uses in building materials, automotive and domestic applications, …), sensors (especially pH electrodes), glassware for laboratories as well as domestic use, etc. Since over 50 years from the discovery of the bioactive glasses by L. Hench, bioglasses are increasingly used in hard tissue engineering but also in several applications including soft tissue engineering. Bioglasses, once doped with adequate ions, can get antimicrobial activity or can enhance the healing rate or the vascularization of the new tissues. The surface modification of the glasses can be exploited to induce new functionalities of the surfaces. It is well known that coatings are already implemented in several industries, such as automotive or pharmaceutics. For instance, automotive glass windows are coated with various layers to assure specific properties including: antiadherence, self-cleaning, antifogging, antireflection, etc. But, new surface modifications are still desired and needed. Thus, adherent or antiadherent surfaces are expected to be useful in specific forensic applications to take fingerprints or to avoid their tendency to remain on different surfaces; sensitive surfaces able to specifically adsorb analytes (including heavy metals, dyes, antibiotics, pesticides, etc.) for the specific accumulation of these analytes and finally to analyze them by specific techniques. Multiple areas can be specifically modified to develop arrays with complex sensing activity. In the current work, we are focusing our researches in modifying the surface of the glass slides by a self-assembled methodology, as schematically presented in Fig 1.
硅酸盐基材料的新视角:从玻璃的经典到新兴应用
硅和氧是地球上最丰富的元素,主要以硅酸盐的形式存在于自然界。在许多应用中,为许多特定应用生产了大量的玻璃。然而,也有一些新兴的应用越来越受到人们的关注。玻璃的经典应用包括窗户(汽车,房屋等),玻璃纤维和织物(用于建筑材料,汽车和家庭应用的树脂基复合材料,…),传感器(特别是pH电极),实验室和家庭使用的玻璃器皿等。自L. Hench发现生物活性玻璃50多年以来,生物玻璃在硬组织工程和软组织工程等领域的应用越来越广泛。生物玻璃,一旦掺杂足够的离子,可以获得抗菌活性或可以提高愈合速度或新组织的血管化。玻璃的表面改性可以用来诱导表面的新功能。众所周知,涂料已经应用于汽车或制药等多个行业。例如,汽车玻璃窗涂有不同的层,以确保特定的性能,包括:抗粘附,自清洁,防雾,抗反射等。但是,新的表面修饰仍然是需要的。因此,粘附或反粘附表面有望在特定的法医应用中有用,以获取指纹或避免其留在不同表面上的倾向;能够特异性吸附分析物(包括重金属、染料、抗生素、农药等)的敏感表面,以便这些分析物的特异性积累,并最终通过特定技术对其进行分析。可以对多个区域进行专门修改,以开发具有复杂传感活性的阵列。在目前的工作中,我们的研究重点是通过一种自组装的方法来修饰玻片的表面,如图1所示。
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