{"title":"Laser-Induced Breakdown Spectroscopy for Nuclear Fuel Material","authors":"K. Akaoka, M. Miyabe, H. Otobe, I. Wakaida","doi":"10.2184/LSJ.42.12_918","DOIUrl":null,"url":null,"abstract":"るためには非常に高い分解能の分光器を必要とする.こ の様な複雑に混在する 含有燃料を模擬するために, アクチノイドと同様に最外殻の s 軌道電子が占有され閉 能の分光器を用いてスペクトルの測定を行い,解析では 定量性を高めるために測定されたスペクトルをデコンボ For the remote analysis of a next generation nuclear fuel material containing minor actinide (MA), we applied laser-induced breakdown spectroscopy (LIBS) to uranium oxide (U 3 O 8 ), which included a small amount of neodymium oxide (Nd 2 O 3 ), as a simulated sample of MA. By using a deconvolution technique for the Nd spectra in U, we separated the complex, overlapped, and confused spectra and determined their actual intensities. As a result, a calibration curve with good linearity and a detection limit of less than 700 ppm were demonstrated.","PeriodicalId":308244,"journal":{"name":"The Review of Laser Engineering","volume":"1 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2014-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Review of Laser Engineering","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2184/LSJ.42.12_918","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
Abstract
るためには非常に高い分解能の分光器を必要とする.こ の様な複雑に混在する 含有燃料を模擬するために, アクチノイドと同様に最外殻の s 軌道電子が占有され閉 能の分光器を用いてスペクトルの測定を行い,解析では 定量性を高めるために測定されたスペクトルをデコンボ For the remote analysis of a next generation nuclear fuel material containing minor actinide (MA), we applied laser-induced breakdown spectroscopy (LIBS) to uranium oxide (U 3 O 8 ), which included a small amount of neodymium oxide (Nd 2 O 3 ), as a simulated sample of MA. By using a deconvolution technique for the Nd spectra in U, we separated the complex, overlapped, and confused spectra and determined their actual intensities. As a result, a calibration curve with good linearity and a detection limit of less than 700 ppm were demonstrated.
这就需要分辨率非常高的分光器。为了模拟这种复杂混合的含有燃料,与锕系元素一样,使用占据最外层s轨道电子的闭合光谱仪进行光谱测定,在分析中,为了提高定量性,对测量的光谱进行解组合For the remote analysis of a next generation nuclear fuel material容器minor actinide (MA),we applied laser-induced breakdown spectroscopy (LIBS) to uranium oxide (u3o8),which included a small amount of neodymium oxide (Nd 2 O 3),as a simulated sample of MA. By using a deconvolution technique for the Nd spectra in U,we separated the complex, overlapped,and confused spectra and determined their actual intensities. As a result,calibration curve with good linearity and a detection limit of less than 700ppm weredemonstrated。