Precipitated calcium oxide nanosize from limestone and blood clam shells

C. Pujiastuti, Srie Muljani, K. Sumada
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Abstract

Calcium oxide (CaO) is a product that is needed by various types of industries such as the pharmaceutical, chemical, agricultural and health industries. CaO is generally produced by the calcination method of CaCO3 materials such as calcium carbonate rocks or from various types of shells. The calcination method requires a large amount of energy because the operating temperature is above 1000 C and the resulting calcium oxide product is still micrometer size. This study developed nanosize precipitated CaO from two calcium sources, namely blood clam shells and limestone. For clam shells using hydrochloric acid as a solvent and sodium hydroxide as a precipitating agent, while for limestone using phosphoric acid as a solvent and potassium hydroxide as a precipitating agent. The effect of acidity (pH) and calcination temperature on the characteristics of the precipitated CaO was observed. The blood calm shell produces precipitated CaO 85-92 % with a particle size of 200-250 Nm and the limestone produces precipitated CaO 42-66% with a particle size of 250-300 Nm 
石灰石和血蛤壳中沉淀的纳米级氧化钙
氧化钙(CaO)是制药、化工、农业、卫生等各行各业都需要的产品。CaO一般由碳酸钙岩石等CaCO3材料煅烧法或从各种类型的贝壳中生产。煅烧法需要大量的能量,因为操作温度在1000℃以上,所得到的氧化钙产品仍然是微米大小。本研究从血蛤壳和石灰石两种钙源中制备了纳米级沉淀CaO。对于蛤壳,使用盐酸作为溶剂,氢氧化钠作为沉淀剂,而对于石灰石,使用磷酸作为溶剂,氢氧化钾作为沉淀剂。考察了酸度(pH)和煅烧温度对沉淀CaO特性的影响。血静壳产生沉淀CaO 85 ~ 92%,粒径200 ~ 250 Nm;石灰石产生沉淀CaO 42 ~ 66%,粒径250 ~ 300 Nm
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