Novel Expanding Metal Alloy for Non-Elastomeric Sealing and Anchoring

M. Fripp, R. Evers, S. Greci, B. Least, Christopher Pelto, Christopher Rodriguez, T. Stein, Lori Wiltz, Allan Zhong
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Abstract

A new class of expanding isolation systems has been enabled by the creation of a uniquely engineered expanding metal alloy. The engineered metal alloy expands downhole and chemically transforms from a metal alloy into a rock-like seal. This novel metal alloy results in a sealing system that combines the operational simplicity of swellable elastomers with the robustness of non-elastomeric seals and includes an anchoring capability to the seal. Swellable elastomers have provided effective zonal isolation since their introduction in the early 2000s. Swellable elastomers expand by absorbing fluids within the matrix of the elastomer. This absorption causes the swellable elastomer to expand in size and results in a high-pressure seal for zonal isolation. Despite the widespread success of swellable packers, for some applications a non-elastomeric seal for zonal isolation is preferred and more reliable. Applications benefit from non-elastomeric seals for zonal isolation due to temperature, pressure, or chemical compatibility reasons. Other applications, such as fluid injection operations, require anchoring capabilities which can be challenging with swellable elastomers. The new engineered metal alloy chemically reacts with the downhole water-based fluids and expands into a strong rock-like material that provides non-elastomeric zonal isolation with pressure and anchoring capabilities exceeding swellable technology at higher expansion ratios. In addition, water swellable elastomers are not suitable for applications which have a high salinity brine or produced water as the setting fluid. By contrast the expanding metal alloy chemical reaction is enhanced by increasing salinity. The expanding metal alloy bonds with the water-based fluid in the wellbore and this chemical reaction causes the metal to expand into a rock-like material. The chemical reaction results in a new material that is larger than the original alloy. Unlike a swellable elastomer which absorbs fluids (a purely physical process governed by thermodynamics and osmosis), the metal alloy's molecular structure chemically transforms, incorporating the water molecules to create a new material. The metal alloy can expand over 80% as it transforms into its final state as a rock-like seal. Extensive small-scale and full-scale tests were conducted to reliably and consistently map the metamorphosis from the engineered metal alloy into the rock-like material. These tests required developing new methods for testing the material including designing new test fixtures and new test procedures. Testing proved seals were created in smooth cylinders as well as in irregular shapes and with a wide range of brine types and brine concentrations. The result is an expanding engineered alloy that creates a robust and durable seal with anchoring capabilities across a wide range of downhole conditions. A novel non-elastomeric zonal isolation system is composed of a new expanding metal alloy that expands in water-based wellbore fluid, completion fluid, or formation fluid. The performance of this new material has been demonstrated through experimental testing. This paper discusses the development and initial testing of this new expanding metal and the process of forming a robust and reliable downhole seal with anchoring capabilities.
新型非弹性密封与锚固用膨胀金属合金
一种新型的膨胀隔离系统是由一种独特设计的膨胀金属合金制成的。这种经过改造的金属合金在井下膨胀,通过化学反应从金属合金转变为类似岩石的密封材料。这种新型金属合金形成的密封系统,结合了可膨胀弹性体的操作简单性和非弹性体密封的坚固性,并具有密封的锚定能力。自21世纪初引入以来,可膨胀弹性体提供了有效的层间隔离。可膨胀弹性体通过吸收弹性体基质内的流体而膨胀。这种吸收导致可膨胀弹性体的尺寸膨胀,从而实现层间隔离的高压密封。尽管可膨胀封隔器取得了广泛的成功,但在某些应用中,用于层间隔离的非弹性密封更为可靠。由于温度、压力或化学相容性的原因,非弹性密封可以用于层间隔离。其他应用,如流体注入作业,需要锚定能力,这对于可膨胀弹性体来说是一个挑战。新型工程金属合金与井下水基流体发生化学反应,膨胀成一种坚固的岩石状材料,提供非弹性层间隔离,在更高膨胀比下,其压力和锚定能力超过可膨胀技术。此外,遇水膨胀弹性体不适用于高盐度卤水或采出水作为坐封液的应用。相反,增加矿化度可增强膨胀金属合金的化学反应。膨胀的金属合金与井筒中的水基流体结合,这种化学反应使金属膨胀成类似岩石的材料。化学反应产生了一种比原合金更大的新材料。与吸收流体的可膨胀弹性体(由热力学和渗透作用控制的纯物理过程)不同,金属合金的分子结构发生了化学变化,将水分子结合在一起,形成了一种新材料。这种金属合金可以膨胀80%以上,最终变成像岩石一样的密封。进行了大量的小规模和全尺寸测试,以可靠和一致地绘制从工程金属合金到岩石状材料的变形图。这些测试需要开发新的方法来测试材料,包括设计新的测试夹具和新的测试程序。测试证明,密封可以在光滑的圆柱体中形成,也可以在不规则形状的圆柱体中形成,可以在各种盐水类型和浓度下形成。结果是一种可扩展的工程合金,创造了坚固耐用的密封件,具有在各种井下条件下的锚固能力。一种新型非弹性层状隔离系统由一种新型膨胀金属合金组成,该合金可在水基井筒流体、完井液或地层流体中膨胀。这种新材料的性能已通过实验测试得到证实。本文讨论了这种新型膨胀金属的开发和初步测试,以及形成具有锚固能力的坚固可靠的井下密封的过程。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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