Improvement of Surface Cracking Risks by Controlling Dilution of Cobalt-Based Hardfacings

T. Yokoyama, T. Kurimura, N. Sakakibara, Fumiyuki Suzuki
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Abstract

Cobalt-based hardfacings have been widely applied to the main valve seats of steam turbines for the purpose of improving durability. With the aim of decreasing the surface cracking risks of the hardfacings, the dilution of the hardfacing on their surface was controlled and the properties of the dilution-controlled materials were investigated in this study. Mixtures of cobalt-based hardfacings and base materials were cast in order to simulate the dilution of base material to hardfacing, which occurs in the process such as PTA welding. It was confirmed that the grain size matched that produced by PTA welding by controlling the cooling rate. To investigate the effect of aging on the microstructures and mechanical properties of the cast samples, the samples were aged in electric furnaces where the temperature was controlled to the steam temperature of steam turbines and above. The test results show that the phase transitioned from face-centered cubic to hexagonal closed-packed in low-dilution samples, while carbides precipitated along the grain boundaries in high-dilution samples after aging. Both samples showed an increase in hardness and reduction in ductility and fracture toughness. In addition, the variation in microstructures and strength properties was suppressed for a 20 % dilution sample. To validate the influence of dilution as investigated with the cast samples, test specimens were machined from the surface and bottom layers of multi-layered hardfacing that had different dilutions by PTA welding. It was confirmed that the influence of dilution on the strength properties of hardfacing layers had a similar tendency to the cast samples. The results above lead to the possibility of reducing the surface cracking risks by controlling the dilution of hardfacings and suppressing embrittlement after aging. We have applied dilution-controlled hardfacings to steam valves and successfully reduced surface cracking.
通过控制钴基堆焊稀释度来降低表面开裂风险
为了提高汽轮机主阀座的耐久性,钴基堆焊已广泛应用于汽轮机主阀座。为了降低堆焊材料的表面开裂风险,控制堆焊材料表面的稀释度,并对稀释控制材料的性能进行了研究。铸造钴基堆焊材料与基体材料的混合物,以模拟在PTA焊接等过程中基体材料对堆焊材料的稀释。通过控制冷却速度,得到与PTA焊接相匹配的晶粒尺寸。为了研究时效对铸态试样组织和力学性能的影响,将铸态试样在温度控制在汽轮机蒸汽温度及以上的电炉中时效。结果表明:低稀释度试样时效后,碳化物沿晶界析出;低稀释度试样时效后,碳化物沿晶界析出;两种样品的硬度都有所增加,但延展性和断裂韧性有所降低。此外,20%稀释样品的微观结构和强度性能的变化被抑制。为了验证稀释对铸态试样的影响,采用PTA焊接方法从不同稀释度的多层堆焊表面和底层加工试样。结果表明,稀释对堆焊层强度性能的影响趋势与铸态相似。以上结果表明,通过控制堆焊面的稀释和抑制时效后脆化来降低表面开裂风险是可能的。我们在蒸汽阀上应用了稀释控制堆焊,成功地减少了表面开裂。
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