Dependence of polyethylene combustion dynamics in a 1 m3 chamber on particle size

N. Poletaev
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Abstract

Introduction. The results of a standard study on the explosion hazard of polyethylene air suspensions (PES) can contribute to the theory of turbulent combustion. For example, analysis of polydispersity data and values of the PES lean combustion limit in a 1 m3 chamber helped to identify the maximum size of explosive particles d*m,t ≈ 100 µm (Poletaev, 2014). In this work, a relationship was obtained between the dynamics of PES combustion in a 1 m3 chamber and the average particle size of the suspension, which is understood as the average particle size of its explosive fraction d*50.Initial data. Well-known findings of a study on the explosion of 28 polyethylene specimens in a 1 m3 chamber were used. Continuous functions of specimen particles distribution by size, necessary for calculating d*50, were represented using the Rosin-Rammler distribution.Combustion dynamics. The dynamics of PES turbulent combustion in a 1 m3 chamber is described by the maximum rate of air suspension burnout Ub. Ub was calculated according to the formula (Kumar, 1992) intended for gas-air mixtures by substituting PES explosion parameters into this formula.Results and its discussion. The graph, describing the dependence of the complex d*50Ub on d*50, is provided. The averaged value of the complex (≈ 45 µm · (m/s)) is constant in the range 40 µm < d*50 < 90 µm. The latter is typical for the product of the particle size and the normal velocity of laminar flame in liquid aerosols (Myers, 1986), which indicates similarity between the effect of particle dispersion and dynamics of turbulent and laminar combustion of the aforementioned heterogeneous mixtures.Conclusions. The dispersive capacity of an explosive polydisperse polyethylene specimen is determined by the average particle size of the explosive fraction of the specimen d*50. The similarity of combustion patterns indicates the proximity of propagation mechanisms typical for turbulent flame, typical for PES, and laminar flame, typical for liquid aerosols.
1 m3燃烧室中聚乙烯燃烧动力学与颗粒大小的关系
介绍。聚乙烯空气悬浮液(PES)爆炸危险性的标准研究结果为紊流燃烧理论提供了理论依据。例如,对1 m3燃烧室中聚醚稀燃烧极限的多分散性数据和值的分析有助于确定爆炸颗粒的最大尺寸d*m,t≈100µm (Poletaev, 2014)。在这项工作中,得到了1 m3燃烧室中PES燃烧动力学与悬浮液的平均粒径之间的关系,即其爆炸分数的平均粒径d*50。初始数据。使用了一项关于28个聚乙烯试样在一个1立方米的腔室中爆炸的著名研究结果。用Rosin-Rammler分布表示样品颗粒按尺寸分布的连续函数,这是计算d*50所必需的。燃烧动力学。用空气悬架最大燃尽率Ub描述了1 m3燃烧室中PES湍流燃烧的动力学。Ub根据(Kumar, 1992)气体-空气混合物公式,将PES爆炸参数代入该公式。结果及其讨论。给出了络合物d*50Ub对d*50的依赖关系图。络合物的平均值(≈45µm·(m/s))在40µm < d*50 < 90µm范围内是恒定的。后者是液体气溶胶中颗粒大小和层流火焰正常速度的典型产物(Myers, 1986),这表明颗粒分散效应与上述非均质混合物湍流和层流燃烧动力学之间的相似性。爆炸性多分散聚乙烯试样的分散能力由试样爆炸部分的平均粒径d*50决定。燃烧模式的相似性表明典型的湍流火焰(典型的PES)和层流火焰(典型的液体气溶胶)的传播机制接近。
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