Effect of Cell Morphology on the Properties of Microcellular Foamed PVC/Wood-Fiber Composites

L. Matuana, Chul B. Park, J. Balatinecz
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引用次数: 6

Abstract

Wood-fiber composites make use of cellulose fibers as a reinforcing filler in the polymer matrix and are known to have a lower material cost and a higher stiffness compared to neat polymers. However, the lower material cost and enhanced stiffness of wood-fiber composites are achieved at the expense of other properties such as the ductility and the impact strength. Since microcellular plastics exhibit a higher relative impact strength, higher relative toughness, and increased relative fatigue life compared to unfoamed plastics, microcellular foaming of wood-fiber composites will improve the mechanical properties of the composites and therefore increase the usefulness of the materials. In this paper, microcellular foamed PVC/wood-fiber composites with unique cell morphology and material composition are characterized. Microcellular structures are produced in PVC/wood-fiber composites by first saturating the composite samples with CO2 under high pressure followed by rapidly decreasing the solubility of gas in the samples. The void fraction of the microcellular foamed PVC/wood-fiber composites is controlled by tailoring the composition of materials and the foaming process parameters. The results indicate that tensile and impact properties of microcellular foamed PVC/wood-fiber composites are most sensitive to changes in the cell morphology and the surface modification of fibers.
细胞形态对微孔发泡PVC/木纤维复合材料性能的影响
木纤维复合材料在聚合物基体中使用纤维素纤维作为增强填料,与纯聚合物相比,具有较低的材料成本和较高的刚度。然而,较低的材料成本和增强的木纤维复合材料的刚度是以牺牲其他性能如延展性和冲击强度为代价的。由于与未发泡塑料相比,微孔塑料具有更高的相对冲击强度、更高的相对韧性和更长的相对疲劳寿命,因此木纤维复合材料的微孔发泡将改善复合材料的机械性能,从而增加材料的有用性。本文研究了具有独特细胞形态和材料组成的聚氯乙烯/木纤维微孔发泡复合材料。微孔结构是在PVC/木纤维复合材料中产生的,首先在高压下用CO2使复合材料样品饱和,然后迅速降低样品中气体的溶解度。通过调整材料的组成和发泡工艺参数,控制PVC/木纤维微孔发泡复合材料的孔隙率。结果表明,微孔发泡PVC/木纤维复合材料的拉伸和冲击性能对微孔发泡PVC/木纤维的细胞形态变化和表面改性最为敏感。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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