Improved Performance of Natural Dye for Eco-friendly Solar Cell Application using SnO2 Nanoparticles by Chemical Precipitation Method

P. Backialakshmi, C. Gopinathan
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引用次数: 2

Abstract

Natural dye-sensitized solar cells (NDSSCs) have gained important interest in the field of solar energy owing to their low production cost, simple fabrication and good efficiency. In the present study, SnO 2 nanoparticles were prepared by chemical precipitation method. The photoanode is fabricated using doctor-blade technique. In this paper, the dye molecules absorb light and make excited electrons the technique adopted, which in revolve create current in the output terminals of the cell. Graphite coated glass was used as the counter electrode. The prepared nanoparticles are characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), and UV-Visible spectroscopy. XRD analysis confirms the structure of tetragonal structure with rutile phase, and crystallite sizes 20-30 nm. Curcuma longa dye extract used as photosensitizer. FTIR results show the M-O (Sn-O) bond with no other distinct impurities from the chemical reactions that were used for SnO 2 preparation. Finally, photocurrent-voltaic characterization of nano-crystaline natural dye solar cell using I-V studies. It was found that the levels of short-circuit current (Jsc), open-circuit voltage (Voc), fill factor (FF) and overall conversion efficiency (η) of Curcuma longa dye extract. Further suggestions to improve the efficiency of NDSSC are discussed.
化学沉淀法制备SnO2纳米颗粒用于环保太阳能电池的天然染料
天然染料敏化太阳能电池(ndssc)因其生产成本低、制作简单、效率高等优点而受到太阳能领域的广泛关注。本研究采用化学沉淀法制备了二氧化钛纳米颗粒。采用医生刀技术制备光阳极。本文采用的技术是染料分子吸收光并产生受激电子,从而在电池的输出端产生电流。采用石墨涂层玻璃作为对电极。采用粉末x射线衍射(XRD)、扫描电子显微镜(SEM)、能量色散x射线能谱(EDX)和紫外可见光谱对制备的纳米颗粒进行了表征。XRD分析证实其结构为金红石相的四方结构,晶粒尺寸为20 ~ 30 nm。姜黄染料提取物用作光敏剂。FTIR结果表明,与制备sno2的化学反应相比,M-O (Sn-O)键没有其他明显的杂质。最后,利用I-V研究了纳米晶体天然染料太阳能电池的光电特性。研究了姜黄染料提取物的短路电流(Jsc)、开路电压(Voc)、填充系数(FF)和总转化效率(η)的变化规律。进一步探讨了提高NDSSC效率的建议。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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