Increasing of the steels properties by an ecological method of isothermal and step quenching

L. Malinov, V. Malinov, D. Burova
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Abstract

The relevance. Improving the mechanical properties of steels makes it possible to increase the service life of machine parts, which is an important task in materials science. One of the promising directions in its solution is to obtain in steel a multiphase structure, one of the main components of which is metastable austenite, which undergoes a dynamic deformation martensitic transformation (DDMT) - self-hardening effect under loading (SHL). Methods providing the required structure are isothermal and step quenching. However, at present, when they are carried out for cooling from the austenitizing temperature and holding at the constant temperature used non-environmentally friendly substances: heated oil, molten salts or alkalis. In this regard the actual problem is the exclusion of them from the technological process. The possibility of solving this problem on several steels has shown. Purpose is to show the possibility of increasing the mechanical properties of the studied steels 30ХГСА, 38ХС, 45Г, 40ХН, 10Г12, 60Х18 by using rational modes of an environmentally friendly method of steels quenching (isothermal - for low-alloyed and step - for high-alloyed) due to obtaining in their structure along with other components of metastable residual austenite and the implementation of the SHL effect. Research methods. Samples of the investigated steels after austenitization (in some cases with holding in IСIT) were cooled in water to the temperature of lower bainite formation (isothermal quenching) or stabilization of supercooled austenite to martensitic transformation upon cooling (step quenching), after which they were kept in a furnace and cooled in air to room temperature. Durometric, metallographic and X-ray research methods were used. The tensile properties and impact strength were determined. These properties were compared with those obtained for the studied steels after a typical heat treatment, including quenching in oil and tempering. Results. It is shown that isothermal and step quenching of the investigated steels without the use of non-environmentally friendly substances, carried out according to rational modes, makes it possible to increase the mechanical properties in comparison with their level after the commonly used quenching in oil (fire hazard, the vapors are cancerogenic) and tempering. This is achieved by obtaining a multiphase structure with metastable austenite. Scientific novelty. It is proposed to obtain a multiphase structure with metastable austenite in them to improve the mechanical properties of the studied steels by conducting isothermal and step quenching in an environmentally friendly way without using heated oil, molten salts or alkalis. Practical value. For the studied steels the modes of isothermal and step quenching are determined in an environmentally friendly way, which make it possible to increase the mechanical properties in comparison with the level achieved by quenching and tempering. Wherein in contrast to a similar typical quenching method are excluded the costs of purchasing salts or alkalis, their disposal and washing of products from them. Compared to quenching and tempering, the new method does not require the use of oil and tempering. The latter improves ecology and reduces energy consumption during heat treatment.
采用等温阶梯淬火生态法提高钢的性能
的相关性。提高钢的力学性能,使机械零件的使用寿命得以延长,是材料科学的重要课题。在钢中获得以亚稳奥氏体为主要成分之一的多相组织,发生动态变形马氏体相变(DDMT) -加载自硬化效应(SHL)是解决这一问题的一个有希望的方向。提供所需结构的方法是等温淬火和阶梯淬火。然而,目前,当它们从奥氏体化温度进行冷却和恒温保温时,使用的是非环保物质:加热油、熔盐或碱。在这方面,实际问题是将它们排除在技术过程之外。在几种钢上解决这个问题的可能性已经显示出来。目的是显示通过使用合理的环境友好钢淬火方法(等温-低合金和阶梯-高合金)的方式来提高所研究钢30ХГСА, 38ХС, 45Г, 40ХН, 10Г12, 60Х18的机械性能的可能性,因为在其结构中获得了亚稳残余奥氏体的其他成分,并实现了SHL效应。研究方法。在奥氏体化(在某些情况下,在IСIT中保温)后,将所研究的钢样品在水中冷却到下贝氏体形成的温度(等温淬火)或冷却时过冷奥氏体到马氏体转变的稳定温度(阶梯淬火),之后将其保存在炉中并在空气中冷却到室温。采用了硬度学、金相学和x射线研究方法。测定了材料的拉伸性能和冲击强度。这些性能与经过典型热处理(包括油淬和回火)后得到的性能进行了比较。结果。结果表明,在不使用非环保物质的情况下,按照合理的方式对所研究的钢进行等温和阶梯淬火,与常用的油淬(有火灾危险,蒸汽致癌)和回火相比,可以提高钢的力学性能。这是通过获得具有亚稳奥氏体的多相结构来实现的。科学的新奇。建议在不使用加热油、熔盐或碱的情况下,采用环境友好的等温和阶梯淬火方法,获得含有亚稳奥氏体的多相结构,以改善所研究钢的力学性能。实用价值。对于所研究的钢,以一种环保的方式确定了等温和阶梯淬火的模式,这使得与淬火和回火所达到的水平相比,有可能提高机械性能。其中,与类似的典型淬火方法相比,不包括购买盐或碱、处理它们以及从中洗涤产品的成本。与淬火回火相比,新方法不需要使用油和回火。后者改善了生态环境,减少了热处理过程中的能耗。
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