Enhanced thermal stability of electro-optic polymer modulator

H. Miura, S. Yokoyama
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Abstract

We synthesized the EO polymer having a glass transition temperature (Tg) higher than 190°C. The fabricated waveguide modulator was tested for the thermal and temporal stability at 105 °C for longer than 2000 hours. The EO activity of the measured polymer modulator is attributed to the high molecular hyperpolarizability of the used chromophores, and thermal stability to the high Tg of the EO polymer.
提高电光聚合物调制器的热稳定性
我们合成了玻璃化转变温度(Tg)高于190℃的EO聚合物。制作的波导调制器在105℃下进行了超过2000小时的热稳定性和时间稳定性测试。所测聚合物调制剂的EO活性归因于所使用的发色团的高分子超极化性,以及EO聚合物的高Tg热稳定性。
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