Titanium dioxide nanoparticles in nutrient solution for enhancement of power density generated from plant fuel cell

Kanokporn Sompornpailin, S. Siri
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Abstract

Plants have ability to convert solar energy into chemical energy in photosynthetic process to produce their own food. Under this process, chlorophyll molecules in plant cell are excited and cascade transferring a high energy electron to the accepters, therefore the electrical currents are generated in this plant system. This current is thinking as the alternative power resources in the future. Titanium dioxide (TiO2) is widely used in photocatalysis in semiconductors because of large bandgap polymorphs of this particles. This substance enhances an absorbing light of different wavelengths owing to their electronic structure. In this experiment, TiO2 nanoparticles are added up into different concentrations of nutrient solution under plant fuel cell system, in order to study the generation of electric power. The cathode and anode electrodes, in the system were zinc steel and polypropylene mixed with CNTs. Electrical potentials and currents of plant fuel cell system with TiO2 are detected and recorded in comparison to that of system without TiO2. Plant fuel cell system, adding TiO2 nanoparticles enhances the current density and voltage in comparison to the non TiO2 system, depending on the concentration of nutrient solution medium and detection time. TiO2 nanoparticle adding in liquid nutrient of plant fuel cell enhance the electric power density, because this particle may improve an absorption of light radiation. The process may increase the oxidation of water and soluble nutrients which escalate the level of total ionic charges in the fuel system. The charges were separated and transferred to the specific electrodes that will be affected on power density generating from the fuel cell system.
营养液中二氧化钛纳米颗粒提高植物燃料电池发电功率密度
植物有能力在光合作用过程中将太阳能转化为化学能来生产自己的食物。在这个过程中,植物细胞中的叶绿素分子被激发并级联传递一个高能电子给受体,从而在植物系统中产生电流。这种电流被认为是未来的替代能源。二氧化钛(TiO2)由于具有较大的带隙多晶而被广泛应用于半导体的光催化。这种物质由于其电子结构增强了对不同波长光的吸收。本实验在植物燃料电池系统下,将TiO2纳米粒子加入到不同浓度的营养液中,研究其发电效果。该系统的阴极和阳极电极分别为锌钢和聚丙烯混合CNTs。检测并记录添加TiO2的植物燃料电池系统与不添加TiO2的植物燃料电池系统的电势和电流。植物燃料电池系统中,添加TiO2纳米粒子相比于不添加TiO2的系统,电流密度和电压都有所提高,这取决于营养液介质的浓度和检测时间。在植物燃料电池液体营养物中加入TiO2纳米颗粒,可以提高电池的电功率密度,因为TiO2纳米颗粒可以提高电池对光辐射的吸收。该过程可能会增加水和可溶性营养物质的氧化,从而使燃料系统中的总离子电荷水平升高。电荷被分离并转移到特定的电极上,这将影响燃料电池系统产生的功率密度。
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