SPECIFICS OF AGING OF OXIDIZED OIL BITUMEN PRODUCED IN UKRAINE

M. Donchenko, O. Grynyshyn
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Abstract

Despite to the significant advantages of asphalt concrete coating in comparison with other types of coatings, such as high mechanical strength and roughness; low rigidity of the coating; high ability to absorb vibrations, etc., there are also significant disadvantages of asphalt concrete. Among the main ones is the short term of use, which manifests itself in the breaking and destruction of the roadway after several changes of seasons. The reason for this phenomenon is the complex effect of natural and mechanical factors, which finally lead to different types of chemical and structural changes in the binder of the asphalt, which also called aging of bitumen. The aging process of the binder begins long before the bitumen gets into the asphalt. Since the main part of the Ukrainian binders is obtained by the oxidation of tar, the conditions of the oxidation process play an important role for further transformation. In addition, there are internal irreversible reactions in bitumen, which occur under the influence of oxygen, heat, low temperatures and light. To evaluate the intensity of bitumen aging in the coating, we investigated the change of bitumen properties before and after warming, which allows simulate the thermal oxidation of bitumen - in a thin layer of binder (2 mm) at 163°C for 5 or 10 hours. As the simple we used Ukrainian bitumen of the BND 60/90. Thereafter, a comparison of baseline data and indexes, determined after the aging was performed to evaluate changes due to the aging of bitumen. are weight loss and softening temperature change, needle penetration (penetration), brittleness and elongation (ductility), determined by standard methods. Structural-group analysis, infrared spectroscopy of the original bitumen and aged for control in the aging
乌克兰氧化沥青老化的具体情况
尽管沥青混凝土涂层与其他类型的涂层相比具有显着的优点,例如高机械强度和粗糙度;涂层刚性低;吸收振动能力高等优点,沥青混凝土也有明显的缺点。其中最主要的是短期使用,表现为经过几次季节变化后道路的断裂和破坏。产生这种现象的原因是自然因素和机械因素的复杂作用,最终导致沥青的粘结剂发生不同类型的化学和结构变化,也称为沥青老化。粘结剂的老化过程早在沥青进入沥青之前就开始了。由于乌克兰粘合剂的主要部分是由焦油氧化得到的,因此氧化过程的条件对进一步转化起着重要作用。此外,沥青内部还存在不可逆反应,这些不可逆反应在氧气、热、低温和光的作用下发生。为了评估涂层中沥青老化的强度,我们研究了加热前后沥青性能的变化,可以模拟沥青在163°C下在薄层粘合剂(2mm)中热氧化5或10小时。简单地说,我们使用了BND 60/90的乌克兰沥青。然后,对比老化后确定的基线数据和指标,评价沥青老化造成的变化。均有失重和软化,温度变化,穿针(渗透),脆性和伸长率(延展性),由标准方法测定。结构-基团分析,红外光谱分析原始沥青和老化后的控制
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