Advancements of non-viologen-based anolytes for pH-neutral aqueous organic redox flow batteries

Chemical Synthesis Pub Date : 1900-01-01 DOI:10.20517/cs.2023.07

Hong Sun, Feiyang Hu, Zirui Jiang, Zhiwen Cui, Mahalingam Ravivarma, Hao Fan, Jiangxuan Song, D. Kong

{"title":"Advancements of non-viologen-based anolytes for pH-neutral aqueous organic redox flow batteries","authors":"Hong Sun, Feiyang Hu, Zirui Jiang, Zhiwen Cui, Mahalingam Ravivarma, Hao Fan, Jiangxuan Song, D. Kong","doi":"10.20517/cs.2023.07","DOIUrl":null,"url":null,"abstract":"Aqueous organic redox flow battery (AORFB) is regarded as the most promising next-generation technology for energy storage that stores electricity in redox-active organics lysed in mild salt-electrolytes. Composed of abundant elements such as C, H, O, and N, the adapted organics have a high degree of structural diversity and tunability, endowing it possible to modulate the physicochemical properties of water solubility, redox potential, and stability, and resulting in potential cost-effectiveness, ecological and environmental safety. Therefore, the designable organics consumedly expand the distance for exceeding battery behaviors in comparison with the inorganic counterparts. Herein, this study presents an overview of pH-neutral AORFBs that employ nonflammable water-soluble molecules with cheap inorganic salts as supporting electrolytes. Particular emphasis is given to the progress of molecular engineering design and synthesis of non-viologen-based organic anolytes and their respective AORFB performance. Additionally, some comments on present opportunities and perspectives of this ascendant domain are also demonstrated.","PeriodicalId":381136,"journal":{"name":"Chemical Synthesis","volume":"42 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.20517/cs.2023.07","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

Abstract

Aqueous organic redox flow battery (AORFB) is regarded as the most promising next-generation technology for energy storage that stores electricity in redox-active organics lysed in mild salt-electrolytes. Composed of abundant elements such as C, H, O, and N, the adapted organics have a high degree of structural diversity and tunability, endowing it possible to modulate the physicochemical properties of water solubility, redox potential, and stability, and resulting in potential cost-effectiveness, ecological and environmental safety. Therefore, the designable organics consumedly expand the distance for exceeding battery behaviors in comparison with the inorganic counterparts. Herein, this study presents an overview of pH-neutral AORFBs that employ nonflammable water-soluble molecules with cheap inorganic salts as supporting electrolytes. Particular emphasis is given to the progress of molecular engineering design and synthesis of non-viologen-based organic anolytes and their respective AORFB performance. Additionally, some comments on present opportunities and perspectives of this ascendant domain are also demonstrated.

查看原文本刊更多论文

ph中性水相有机氧化还原液流电池非紫罗兰碱基阳极液的研究进展

水相有机氧化还原液流电池(AORFB)被认为是最有前途的下一代储能技术，它将电能储存在在温和盐电解质中裂解的氧化还原活性有机物中。适应性有机物由丰富的C、H、O、N等元素组成，具有高度的结构多样性和可调性，使其可以调节水溶性、氧化还原电位和稳定性等理化性质，具有潜在的成本效益和生态环境安全性。因此，与无机物相比，可设计的有机物大大扩大了超越电池行为的距离。在此，本研究概述了采用不可燃水溶性分子和廉价无机盐作为支撑电解质的ph中性aorfb。重点介绍了分子工程设计和合成非紫罗兰素基有机电解质的进展及其各自的AORFB性能。此外，还对这一上升领域的当前机遇和前景进行了一些评论。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Chemical Synthesis

CiteScore

3.40

自引率

0.00%

发文量