POROUS CARBON FROM PINEAPPLE PEEL AS ELECTRODE MATERIAL OF SUPERCAPACITOR

Samuel Elean, Suhanan Suhanan, T. Ariyanto
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Abstract

Porous carbon from biomass has a great potential to be developed. Biomass as a resource is renewable, abundantly available, and cheap. One application of porous carbon is as an electrode material of supercapacitor due to its advantageous pore properties such as high specific surface area and pore volume. This research prepared porous carbon material from pineapple peel waste and tested it as a supercapacitor electrode. The research steps were material preparation, conversion of pineapple peel to porous carbon, and characterization, including material characterization and electrochemical characterizations. Pineapple peel (under 80 mesh size) was pre-carbonized by hydrothermal method at 1900C for 2 hours under a subcritical condition. After that, biochar was pyrolyzed at 9000C and activated using CO2/N2 (KB-900-50). As a reference, biochar was also pyrolyzed under a nitrogen atmosphere at 9000C without activation (KB-900). Produced porous carbon was characterized (i) pore structures, e.g., specific surface area, average pore diameter, and total pore volume using N2-sorption analysis, and (ii) electrochemical performance, e.g., cyclic voltammetry and galvanostatic method using 1 M H2SO4 electrolyte solution. The result showed that the activation process effectively increased the porosity of porous carbon. Material (KB-900-50) possesses a high surface area of 648 m2/g and a high capacitance value of 78 F/g.
菠萝皮多孔碳作为超级电容器的电极材料
生物质多孔碳具有很大的开发潜力。生物质作为一种可再生资源,储量丰富,价格低廉。多孔碳具有高比表面积和孔容等优越的孔隙特性,可作为超级电容器的电极材料。本研究以菠萝皮废料为原料制备多孔碳材料,并对其作为超级电容器电极进行了测试。研究步骤包括材料制备、菠萝皮转化成多孔碳以及表征,包括材料表征和电化学表征。采用水热法对80目以下的菠萝皮进行预碳化,温度为1900℃,亚临界条件下预碳化2小时。之后,生物炭在9000C下热解,并使用CO2/N2 (KB-900-50)活化。作为参考,生物炭也在9000C的氮气气氛下进行了无活化热解(KB-900)。采用n2吸附法对制备的多孔碳进行了表征:(1)孔结构,如比表面积、平均孔径和总孔体积;(2)电化学性能,如循环伏安法和恒流法,使用1 M H2SO4电解质溶液。结果表明,活化过程有效地提高了多孔炭的孔隙率。材料(KB-900-50)具有648 m2/g的高表面积和78 F/g的高电容值。
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