The Aluminum Production Process is Optimized by Electrolysis Method

Rong Fu
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Abstract

Electrolysis is a redox reaction under the action of an electric field. Preparation of aluminum by electrolysis is using molten sodium aluminum fluoride as a solvent, molten alumina as a solute, carbon as the anode, aluminum solution as the cathode, under the action of the electric field, the temperature is 950°C -970°C, the electrochemical reaction on the poles in the electrolytic cell: 2Al203==4Al302. Anode reaction: 2O2--4e-=02↑ cathode reaction: Al3+3e=Al o The main electrolytic product of the anode is C02 and CO, which may also contain small amounts of HF and parts of solid particulate matter. In order to improve the air quality and meet the emission standards, it is necessary to treat the anode production of the exhaust gas, which can only be discharged into the air before meeting the emission standards. The electrolysis product of the cathode is aluminum, which is purified and clarified in the thermal insulation furnace, cast into aluminum ingot or directly processed into wire billet and profile.
采用电解法对铝的生产工艺进行了优化
电解是电场作用下的氧化还原反应。电解制备铝的方法是以熔融的氟化铝钠为溶剂,熔融的氧化铝为溶质,碳为阳极,铝溶液为阴极,在电场作用下,温度为950℃-970℃,电解槽内两极上的电化学反应:2Al203==4Al302。阳极反应:2O2—4e-=02↑阴极反应:Al3+3e=Al o阳极的主要电解产物为co2和CO,其中还可能含有少量HF和部分固体颗粒物。为了改善空气质量,达到排放标准,必须对废气的阳极生产进行处理,只有在达到排放标准之前才能排放到空气中。阴极的电解产物为铝,在绝热炉中提纯澄清后,浇铸成铝锭或直接加工成线坯和型材。
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