UV and UV+ Water Effects on Mechanical, Thermal and Morphological Properties of Thermoplastic Polyurethane Based Composites

S. Sismanoglu
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Abstract

The degradation times of composite materials containing petroleum-based polymer matrix are quite long in nature and it causes environmental pollution. Researchers focus on producing alternative composite materials with organic and/or inorganic fillers to reduce degradation times in nature. In addition, the mechanical and chemical properties of polymer matrix composites are affected by heat, light, moisture and surface compatibility between matrix and filler. In the light of this information, many researchers examine the mechanical, thermal, morphological and similar properties of organic and/or inorganic filler composites by using artificial aging processes using one or more of the water, UV and temperature parameters. In this study, bentonite with surface modification by epoxysilane agent, and bentonite without any surface modification will be added to the thermoplastic polyurethane (TPU) polymer matrix, which has two different segments, and will be mixed in a twin screw extruder and it will then be shaped by the injection molding process. Artificial aging processes of the obtained composites will be done under UV and UV+water for 2 and 4 weeks, respectively. The reason for choosing UV and UV+water processes is that UV and water processes have not been applied together at the same time and there is not much knowledge in the literature on this subject. Mechanical, thermal and morphological properties of composites were investigated.
UV和UV+水对热塑性聚氨酯基复合材料力学、热学和形态性能的影响
含石油基聚合物基质的复合材料在自然界中降解时间较长,对环境造成污染。研究人员致力于用有机和/或无机填料生产替代复合材料,以减少自然界中的降解时间。此外,聚合物基复合材料的力学和化学性能受热、光、湿以及基体与填料之间的表面相容性的影响。根据这些信息,许多研究人员通过使用一种或多种水、紫外线和温度参数的人工老化过程来研究有机和/或无机填料复合材料的机械、热、形态和类似性能。在本研究中,将表面经过环氧硅烷改性的膨润土和未经表面改性的膨润土加入到具有两个不同段的热塑性聚氨酯(TPU)聚合物基体中,在双螺杆挤出机中混合,然后进行注射成型工艺。将得到的复合材料分别在紫外线和紫外线+水下进行2周和4周的人工老化处理。选择UV和UV+水工艺的原因是UV和水工艺没有同时应用,文献中关于这一主题的知识不多。研究了复合材料的力学性能、热学性能和形态性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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