Production of Supported Carbon Nanoclusters at Laser Ablation of Foam Graphite

S. Kudryashov, S. G. Ionov, N. B. Zorov
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Abstract

Foam graphite is a new and perspective material for laser ablation applications possessing of very low (subcriticai) bulk density and high concentration of nonequilibrium chemically-induced structural defects (vacancies and etc.). It shows “black body” absorbance, very low transversal thermal diffusivity and sound velocity due to its “sandwich-like” structure of graphite crystallites. Equilibrium laser evaporation of the low-density foam graphite occurs in regular air gaps of its “sandwich-like” structure and thus critical state of carbon seems to be produced. The droplet-like structure of critical state has been predicted by theory of condensed matter state earlier. Therefore laser-induced carbon critical state seems to be intensive source of carbon nanoclusters.
泡沫石墨激光烧蚀制备负载型碳纳米团簇
泡沫石墨具有极低的(亚临界)体积密度和高浓度的非平衡化学诱导结构缺陷(空位等),是激光烧蚀应用的一种前景广阔的新型材料。由于石墨晶体呈“三明治状”结构,具有“黑体”吸光度、极低的横向热扩散系数和声速。低密度泡沫石墨的平衡激光蒸发发生在其“三明治状”结构的规则气隙中,从而产生临界碳态。较早的凝聚态理论预测了临界态的类液滴结构。因此,激光诱导的碳临界态似乎是碳纳米团簇的密集来源。
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